Prolific application of green synthesised CdS nanoparticles for the sequestration of cationic dyes from aqueous solution

Abstract

Synthesis of cadmium sulfide (CdS) nanoparticles using watermelon rind aqueous extract was explored for its effectiveness in eliminating Methylene Blue (MB) and Crystal Violet (CV) dyes from water. The synthesised CdS nanoparticles were characterised with XRD, TEM and EDX and found to be around 10 nm in size with spherical shape. A central composite design was developed to optimise independent variables such as pH, contact time and initial concentrations. The developed quadratic model was found to be significant with p-value <0.0001 and lack of fit >0.005 suggesting the reliability of the model. Isotherm modelling analysis revealed that Langmuir and Freundlich's isotherms provided better explanation for the equilibrium data. The loading capacities of the CdS nanoparticles were found be 227.3 and 185.1 mg g-1, respectively for MB and CV. The experimental data showed a good fit with the pseudo-second-order kinetic model, indicating that chemical reactions were the determining factor in controlling the rate-limiting step. Thermodynamic analyses indicated that the process was spontaneous and exothermic. Desorption and regeneration investigations demonstrated that CdS nanoparticles could be successfully regenerated up to 5 times and reused in the adsorption process. The results conclude that the CdS nanoparticles are capable of remediating water containing cationic dyes. KEY WORDS: Watermelon rind, CdS nanoparticles, Synthetic dyes, Adsorption, RSM Bull. Chem. Soc. Ethiop. 2024, 38(3), 631-645.                                                            DOI: https://dx.doi.org/10.4314/bcse.v38i3.7