“Exploring the Inhibitory Potential of Acetoxime-Zinc Chloride Adduct in Saline Environments for Mild Steel Corrosion Protection”

IF 17.7 1区 化学 Q1 CHEMISTRY, MULTIDISCIPLINARY Accounts of Chemical Research Pub Date : 2024-03-12 DOI:10.5006/4398
S. K. Ola, Ishita Chopra, S. Gopalakrishnan, Veena Dhayal
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Abstract

In this work, acetoxime, zinc chloride and acetoxime adduct of zinc chloride, [ZnCl2.2{HON=C(CH3)2}] (ZA) were investigated as corrosion inhibitor's in 3.5%NaCl solution on mild steel. The electrochemical analysis was carried out using polarization measurements and electrochemical impedance technique and surface analysis was done by Scanning electron microscope coupled with Energy-dispersive X-ray spectroscopy. Using surface analysis and electrochemical data it was concluded that an inhibition synergy was developed when ZA was taken instead of acetoxime or zinc chloride alone in solution phase. Scanning electron microscope methods were used to examine the samples surface in the presence of inhibited solutions. The efficiency of inhibition increases with the increasing concentration and attained the values of 97.18% for the 3mM concentration of ZA.
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"探索乙酰氧基肟-氯化锌加合物在盐碱环境中保护低碳钢腐蚀的抑制潜力"
在这项工作中,研究了乙酰肟、氯化锌和乙酰肟氯化锌加合物 [ZnCl2.2{HON=C(CH3)2}] (ZA) 在 3.5%NaCl 溶液中对低碳钢的缓蚀作用。电化学分析采用极化测量法和电化学阻抗技术,表面分析采用扫描电子显微镜和能量色散 X 射线光谱法。利用表面分析和电化学数据得出的结论是,在溶液阶段使用ZA代替乙酰肟或氯化锌时,会产生抑制协同作用。研究人员使用扫描电子显微镜方法来检测存在抑制溶液的样品表面。抑制效率随着浓度的增加而提高,在 3mM 浓度的ZA 中达到了 97.18%。
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来源期刊
Accounts of Chemical Research
Accounts of Chemical Research 化学-化学综合
CiteScore
31.40
自引率
1.10%
发文量
312
审稿时长
2 months
期刊介绍: Accounts of Chemical Research presents short, concise and critical articles offering easy-to-read overviews of basic research and applications in all areas of chemistry and biochemistry. These short reviews focus on research from the author’s own laboratory and are designed to teach the reader about a research project. In addition, Accounts of Chemical Research publishes commentaries that give an informed opinion on a current research problem. Special Issues online are devoted to a single topic of unusual activity and significance. Accounts of Chemical Research replaces the traditional article abstract with an article "Conspectus." These entries synopsize the research affording the reader a closer look at the content and significance of an article. Through this provision of a more detailed description of the article contents, the Conspectus enhances the article's discoverability by search engines and the exposure for the research.
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