Enhancing Performances of the VOXES Bragg Spectrometer for XES Investigations

Abstract

Utilizing a dispersive crystal for X-ray Emission Spectroscopy (XES) significantly enhances the energy resolution when compared with spectroscopy performed with just silicon drift detectors. This high resolution is particularly valuable for studying metals, as it offers essential insights into their electronic structures and chemical environments. Conducting such experiments in the laboratory, as opposed to synchrotron light sources, presents challenges due to the reduced intensities of X-ray tubes and, consequently, low signal rates, with the effect of increasing the acquisition time. In this study, we demonstrate that XES spectra can be acquired within a few hours for a CuNiZn metallic sample alloy while still maintaining a good energy resolution and a large dynamic range. This is achieved with the VOXES spectrometer, developed at INFN National Laboratories of Frascati (LNF), along with a background reduction procedure that enhances the signal from emission lines under study. This study is a showcase for improving the efficiency of XES in tabletop setup experiments.