Study on the Physical Properties of Hydrogen-Doped Natural Gas Based on Equation of State

Ouyang Xin, Chuan Qin, Shiyao Peng, Yuming He, Weijia Wang
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Abstract

As a zero-emission green clean energy, hydrogen energy is an important means to achieve the strategic goal of carbon neutrality and an important part of the energy Internet. Hydrogen-doped natural gas transportation is an economical and feasible scheme to realize long-distance transportation of hydrogen by using the existing natural gas pipeline network. However, the addition of hydrogen to natural gas will cause obvious changes in the physical properties of the transport medium, which will have a certain impact on the transport characteristics and flow measurement of the pipeline. The main problem is that we need to understand the changes of physical properties after natural gas mixed with hydrogen to ensure the safe operation of natural gas pipe network mixed with hydrogen. Based on this situation, this paper takes BWRS equation as the theoretical basis, selects typical natural gas temperament, calculates and solves the physical parameters of natural gas under different hydrogen blending ratios, and compares them with the standard physical reference values. After verification, the results are used to explore the physical properties of hydrogen-doped natural gas with hydrogen blending ratio, temperature and pressure as variables. The relative average absolute value error (RAAD) of the calculated physical properties of hydrogen-doped natural gas in this paper is less than 2% compared with the reference value of standard physical properties, which can provide theoretical data basis for studying hydrogen-doped pipeline transportation, ensuring pipeline transportation safety and hydrogen-doped natural gas metering.
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基于状态方程的掺氢天然气物理性质研究
氢能作为零排放的绿色清洁能源,是实现碳中和战略目标的重要手段,也是能源互联网的重要组成部分。掺氢天然气运输是利用现有天然气管网实现氢气长距离运输的一种经济可行的方案。但是,在天然气中加入氢会使输送介质的物理性质发生明显变化,对管道的输送特性和流量测量产生一定影响。主要问题在于,我们需要了解天然气掺氢后的物理性质变化,以确保天然气管网掺氢后的安全运行。基于这种情况,本文以 BWRS 方程为理论基础,选取典型天然气气质,计算求解不同掺氢比例下天然气的物理参数,并与标准物理参考值进行比较。验证后,以掺氢比例、温度和压力为变量,利用计算结果探索掺氢天然气的物理性质。与标准物理性质参考值相比,本文计算的掺氢天然气物理性质相对平均绝对值误差(RAAD)小于 2%,可为研究掺氢管道运输、保障管道运输安全和掺氢天然气计量提供理论数据依据。
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