Control of NLO and photocatalysis properties based on the use of Sn-doped ZnO thin films for optoelectronics applications

Abstract

Thin films of zinc oxide (ZnO) have unique properties that make them suitable for various applications. In this study, we used a spray pyrolysis process to develop undoped ZnO and ZnO doped with Sn thin films on a glass substrate. We aimed to investigate the effect of Sn concentration on the optical, nonlinear optical, and structural properties of ZnO:Sn thin films. X-ray diffraction analysis revealed that all the deposited ZnO thin films exhibit polycrystalline hexagonal structures well-oriented along the c-axis. The obtained films were transparent in the visible range, with a transmittance between 70% and 80%. The optical energy bandgap values for the films varied from 3.16 eV to 3.29 eV. We also determined the second- and third-order nonlinear susceptibilities, which decreased with increasing Sn concentration. We investigated the photocatalytic activity of the ZnO-doped Sn thin films using methylene blue dye under visible light. Sn doping enhanced the photocatalytic activity of ZnO thin films, with constant rate values of 0.00046 and 0.00074 min${}^{-1}$ for ZnO and ZnO:Sn thin films, respectively.