{"title":"Hydrogenolysis of isosorbide to diols and triols over a heterogeneous SiO2-supported Rh catalyst†","authors":"Pengru Chen , Wataru Onodera , Masato Akatsuka , Yusuke Kita , Masazumi Tamura","doi":"10.1039/d4cy00266k","DOIUrl":null,"url":null,"abstract":"<div><p>Silica-supported Rh (Rh/SiO<sub>2</sub>) was an effective and reusable heterogeneous catalyst for the hydrogenolysis of isosorbide, providing diols and triols in 58% total yield. The yield was higher than those obtained by hydrogenolysis of glucose and sorbitol, confirming the high potential of isosorbide as a biomass-derived intermediate for the synthesis of polyols.</p></div>","PeriodicalId":66,"journal":{"name":"Catalysis Science & Technology","volume":null,"pages":null},"PeriodicalIF":4.4000,"publicationDate":"2024-06-04","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Catalysis Science & Technology","FirstCategoryId":"92","ListUrlMain":"https://www.sciencedirect.com/org/science/article/pii/S2044475324002570","RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q2","JCRName":"CHEMISTRY, PHYSICAL","Score":null,"Total":0}
引用次数: 0
Abstract
Silica-supported Rh (Rh/SiO2) was an effective and reusable heterogeneous catalyst for the hydrogenolysis of isosorbide, providing diols and triols in 58% total yield. The yield was higher than those obtained by hydrogenolysis of glucose and sorbitol, confirming the high potential of isosorbide as a biomass-derived intermediate for the synthesis of polyols.
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A multidisciplinary journal focusing on cutting edge research across all fundamental science and technological aspects of catalysis.
Editor-in-chief: Bert Weckhuysen
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