{"title":"Elemental Aspects of Transition Metals Pertinent to Organometallic Chemistry: Properties, Periodicity, Curiosities, and Related Main Group Issues","authors":"Peter T. Wolczanski*, ","doi":"10.1021/acs.organomet.3c00529","DOIUrl":null,"url":null,"abstract":"<p >This tutorial on transition metal chemistry─sans the lanthanides and actinides─is intended as preliminary information for a high-level undergraduate (UG) inorganic, organometallics, or a comparable first-year graduate (G) course. It features ionization energies (IEs) and comparative nd and (n+1)s orbital energies, electron affinities (EAs), electronegativities (ENs), and covalent radii (c<sub>r</sub>). Redox properties of appropriate aquo complexes (Δ<i>E</i>°<sub>red</sub> = <i>E</i>°(red)) are also included due to their impact on critical properties and reactivity, as are pertinent aspects of the main group elements.</p>","PeriodicalId":56,"journal":{"name":"Organometallics","volume":null,"pages":null},"PeriodicalIF":2.5000,"publicationDate":"2024-03-29","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Organometallics","FirstCategoryId":"92","ListUrlMain":"https://pubs.acs.org/doi/10.1021/acs.organomet.3c00529","RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q2","JCRName":"CHEMISTRY, INORGANIC & NUCLEAR","Score":null,"Total":0}
引用次数: 0
Abstract
This tutorial on transition metal chemistry─sans the lanthanides and actinides─is intended as preliminary information for a high-level undergraduate (UG) inorganic, organometallics, or a comparable first-year graduate (G) course. It features ionization energies (IEs) and comparative nd and (n+1)s orbital energies, electron affinities (EAs), electronegativities (ENs), and covalent radii (cr). Redox properties of appropriate aquo complexes (ΔE°red = E°(red)) are also included due to their impact on critical properties and reactivity, as are pertinent aspects of the main group elements.
期刊介绍：
Organometallics is the flagship journal of organometallic chemistry and records progress in one of the most active fields of science, bridging organic and inorganic chemistry. The journal publishes Articles, Communications, Reviews, and Tutorials (instructional overviews) that depict research on the synthesis, structure, bonding, chemical reactivity, and reaction mechanisms for a variety of applications, including catalyst design and catalytic processes; main-group, transition-metal, and lanthanide and actinide metal chemistry; synthetic aspects of polymer science and materials science; and bioorganometallic chemistry.
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