Study of the Influence of Doping Efficiency of CeO2 Ceramics with a Stabilizing Additive Y2O3 on Changes in the Strength and Thermophysical Parameters of Ceramics under High-Temperature Irradiation with Heavy Ions

Crystals Pub Date : 2024-03-29 DOI:10.3390/cryst14040320
A. Kozlovskiy, Sholpan G. Giniyatova, D. Shlimas, D. Borgekov, Ruslan M. Rspayev, M. Zdorovets
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Abstract

The article outlines findings from a comparative analysis of the effectiveness of doping CeO2 ceramics with a stabilizing additive Y2O3 on alterations in the strength and thermophysical parameters of ceramics under high-temperature irradiation with heavy ions comparable in energy to fission fragments of nuclear fuel, which allows, during high-temperature irradiation, to simulate radiation damage that is as similar as possible to the fission processes of nuclear fuel. During the studies, it was found that the addition of a stabilizing additive Y2O3 to the composition of CeO2 ceramics in the case of high-temperature irradiation causes an increase in stability to swelling and softening because of a decrease in the thermal expansion of the crystal lattice by 3–8 times in comparison with unstabilized CeO2 ceramics. It has been determined that the addition of a stabilizing additive Y2O3 leads not only to a rise in the resistance of the crystal structure to deformation distortions and swelling, but also to a decrease in the effect of thermal expansion of the crystal structure, which has an adverse effect on the structural ordering of CeO2 ceramics exposed to irradiation at high temperatures.
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研究在 CeO2 陶瓷中掺入稳定添加剂 Y2O3 对重离子高温辐照下陶瓷强度和热物理参数变化的影响
文章概述了在重离子高温辐照下,在 CeO2 陶瓷中掺入稳定添加剂 Y2O3 对改变陶瓷强度和热物理参数的有效性的比较分析结果,重离子的能量与核燃料的裂变碎片相当,这样就可以在高温辐照期间模拟与核燃料裂变过程尽可能相似的辐射损伤。研究发现,在高温辐照情况下,在 CeO2 陶瓷的成分中添加稳定添加剂 Y2O3,可使晶体晶格的热膨胀率比未稳定的 CeO2 陶瓷降低 3-8 倍,从而提高对膨胀和软化的稳定性。据测定,添加稳定添加剂 Y2O3 不仅能提高晶体结构对变形扭曲和膨胀的抵抗力,还能降低晶体结构的热膨胀效应,从而对高温辐照下的 CeO2 陶瓷的结构有序性产生不利影响。
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