{"title":"The pKa Values of Water in Water: A Long-Standing, Tiresome, yet Soon Forgotten Issue?","authors":"Antonio Togni","doi":"10.2533/chimia.2024.167","DOIUrl":null,"url":null,"abstract":"The pKa values of water and the hydrogen ion (proton) in water are 14 and 0, respectively. Yet, many textbooks of general, organic, and, to a lesser extent, inorganic chemistry provide the incorrect values 15.74 and -1.74, respectively. This column briefly introduces the long-standing issue of these two different pairs of values, the consequences it bears when teaching general chemistry, and expresses the hope that it may be solved soon.","PeriodicalId":1,"journal":{"name":"Accounts of Chemical Research","volume":"43 23","pages":""},"PeriodicalIF":17.7000,"publicationDate":"2024-03-27","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Accounts of Chemical Research","FirstCategoryId":"92","ListUrlMain":"https://doi.org/10.2533/chimia.2024.167","RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q1","JCRName":"CHEMISTRY, MULTIDISCIPLINARY","Score":null,"Total":0}
引用次数: 0
Abstract
The pKa values of water and the hydrogen ion (proton) in water are 14 and 0, respectively. Yet, many textbooks of general, organic, and, to a lesser extent, inorganic chemistry provide the incorrect values 15.74 and -1.74, respectively. This column briefly introduces the long-standing issue of these two different pairs of values, the consequences it bears when teaching general chemistry, and expresses the hope that it may be solved soon.
期刊介绍：
Accounts of Chemical Research presents short, concise and critical articles offering easy-to-read overviews of basic research and applications in all areas of chemistry and biochemistry. These short reviews focus on research from the author’s own laboratory and are designed to teach the reader about a research project. In addition, Accounts of Chemical Research publishes commentaries that give an informed opinion on a current research problem. Special Issues online are devoted to a single topic of unusual activity and significance.
Accounts of Chemical Research replaces the traditional article abstract with an article "Conspectus." These entries synopsize the research affording the reader a closer look at the content and significance of an article. Through this provision of a more detailed description of the article contents, the Conspectus enhances the article's discoverability by search engines and the exposure for the research.
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