Improved coverage factors for expanded measurement uncertainty calculated from two estimated variance components

IF 0.8 4区 工程技术 Q4 CHEMISTRY, ANALYTICAL Accreditation and Quality Assurance Pub Date : 2024-03-27 DOI:10.1007/s00769-024-01579-w
Peter D. Rostron, Tom Fearn, Michael H. Ramsey
{"title":"Improved coverage factors for expanded measurement uncertainty calculated from two estimated variance components","authors":"Peter D. Rostron,&nbsp;Tom Fearn,&nbsp;Michael H. Ramsey","doi":"10.1007/s00769-024-01579-w","DOIUrl":null,"url":null,"abstract":"<div><p>Measurement uncertainty (MU) arising at different stages of a measurement process can be estimated using analysis of variance (ANOVA) on replicated measurements. It is common practice to derive an expanded MU by multiplying the resulting standard deviation by a coverage factor <i>k.</i> This coverage factor then defines an interval around a measurement value within which the value of the measurand, or true value, is asserted to lie for a desired confidence level (e.g. 95 %). A value of <i>k</i> = 2 is often used to obtain approximate 95 % coverage, although <i>k</i> = 2 will be an underestimate when the standard deviation is estimated from a limited amount of data. An alternative is to use Student’s <i>t-</i>distribution to provide a value for <i>k</i>, but this requires an exact or approximate degrees of freedom (df). This paper explores two different methods of deriving an appropriate <i>k</i> in the case when two variances from an ANOVA (classical or robust) need to be combined to estimate the measurement variance. Simulations show that both methods using the modified coverage factor generally produce a confidence interval much closer to the desired level (e.g. 95 %) when the data are approximately normally distributed. When these confidence intervals do deviate from 95 %, they are consistently conservative (i.e. reported coverage is higher than the nominal 95 %). When outlying values are included at the level of the larger variance component, in some cases the method used for robust ANOVA produces confidence intervals that are very conservative.</p></div>","PeriodicalId":454,"journal":{"name":"Accreditation and Quality Assurance","volume":"29 3","pages":"225 - 230"},"PeriodicalIF":0.8000,"publicationDate":"2024-03-27","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://link.springer.com/content/pdf/10.1007/s00769-024-01579-w.pdf","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Accreditation and Quality Assurance","FirstCategoryId":"5","ListUrlMain":"https://link.springer.com/article/10.1007/s00769-024-01579-w","RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q4","JCRName":"CHEMISTRY, ANALYTICAL","Score":null,"Total":0}
引用次数: 0

Abstract

Measurement uncertainty (MU) arising at different stages of a measurement process can be estimated using analysis of variance (ANOVA) on replicated measurements. It is common practice to derive an expanded MU by multiplying the resulting standard deviation by a coverage factor k. This coverage factor then defines an interval around a measurement value within which the value of the measurand, or true value, is asserted to lie for a desired confidence level (e.g. 95 %). A value of k = 2 is often used to obtain approximate 95 % coverage, although k = 2 will be an underestimate when the standard deviation is estimated from a limited amount of data. An alternative is to use Student’s t-distribution to provide a value for k, but this requires an exact or approximate degrees of freedom (df). This paper explores two different methods of deriving an appropriate k in the case when two variances from an ANOVA (classical or robust) need to be combined to estimate the measurement variance. Simulations show that both methods using the modified coverage factor generally produce a confidence interval much closer to the desired level (e.g. 95 %) when the data are approximately normally distributed. When these confidence intervals do deviate from 95 %, they are consistently conservative (i.e. reported coverage is higher than the nominal 95 %). When outlying values are included at the level of the larger variance component, in some cases the method used for robust ANOVA produces confidence intervals that are very conservative.

查看原文
分享 分享
微信好友 朋友圈 QQ好友 复制链接
本刊更多论文
根据两个估计方差分量计算的扩大测量不确定性的改进覆盖因子
测量过程不同阶段产生的测量不确定度 (MU) 可通过对重复测量进行方差分析 (ANOVA) 来估算。通常的做法是将由此得出的标准偏差乘以覆盖因子 k,从而得出一个扩展的 MU。该覆盖因子定义了测量值周围的一个区间,在该区间内,测量值或真值被认为处于所需的置信水平(例如 95%)。通常使用 k = 2 的值来获得近似 95 % 的覆盖率,不过在根据有限数据估算标准偏差时,k = 2 的值会被低估。另一种方法是使用学生 t 分布来提供 k 值,但这需要精确或近似的自由度 (df)。本文探讨了在需要结合方差分析(经典方差分析或稳健方差分析)中的两个方差来估计测量方差的情况下,推导适当 k 值的两种不同方法。模拟结果表明,当数据近似正态分布时,使用修正覆盖因子的两种方法通常都能得出更接近理想水平(如 95 %)的置信区间。当这些置信区间偏离 95 % 时,它们始终是保守的(即报告的覆盖率高于标称的 95 %)。当在较大方差分量的水平上包含离群值时,在某些情况下,稳健方差分析所使用的方法会产生非常保守的置信区间。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
求助全文
约1分钟内获得全文 去求助
来源期刊
Accreditation and Quality Assurance
Accreditation and Quality Assurance 工程技术-分析化学
CiteScore
1.80
自引率
22.20%
发文量
39
审稿时长
6-12 weeks
期刊介绍: Accreditation and Quality Assurance has established itself as the leading information and discussion forum for all aspects relevant to quality, transparency and reliability of measurement results in chemical and biological sciences. The journal serves the information needs of researchers, practitioners and decision makers dealing with quality assurance and quality management, including the development and application of metrological principles and concepts such as traceability or measurement uncertainty in the following fields: environment, nutrition, consumer protection, geology, metallurgy, pharmacy, forensics, clinical chemistry and laboratory medicine, and microbiology.
期刊最新文献
Correction: Certification of the total element mass fractions in UME EnvCRM 03 soil sample via a joint research project Association between blood lead levels and socio-demographic factors among outpatient children in Ningbo, China Proficiency tests for analysis of pesticide residues in kimchi cabbage and ginseng in South Korea from 2008 to 2020 Points to consider when establishing an equipment calibration programme in a conventional food microbiology laboratory for ISO/IEC 17025:2017 accreditation purpose Approaches for the production of reference materials with qualitative properties—The new International Standard ISO 33406
×
引用
GB/T 7714-2015
复制
MLA
复制
APA
复制
导出至
BibTeX EndNote RefMan NoteFirst NoteExpress
×
×
提示
您的信息不完整,为了账户安全,请先补充。
现在去补充
×
提示
您因"违规操作"
具体请查看互助需知
我知道了
×
提示
现在去查看 取消
×
提示
确定
0
微信
客服QQ
Book学术公众号 扫码关注我们
反馈
×
意见反馈
请填写您的意见或建议
请填写您的手机或邮箱
已复制链接
已复制链接
快去分享给好友吧!
我知道了
×
扫码分享
扫码分享
Book学术官方微信
Book学术文献互助
Book学术文献互助群
群 号:481959085
Book学术
文献互助 智能选刊 最新文献 互助须知 联系我们:info@booksci.cn
Book学术提供免费学术资源搜索服务,方便国内外学者检索中英文文献。致力于提供最便捷和优质的服务体验。
Copyright © 2023 Book学术 All rights reserved.
ghs 京公网安备 11010802042870号 京ICP备2023020795号-1