MoSe2 in flower spheres provides abundant active sites for TiO2 photocatalytic degradation of RhB

IF 17.7 1区 化学 Q1 CHEMISTRY, MULTIDISCIPLINARY Accounts of Chemical Research Pub Date : 2024-03-26 DOI:10.15251/cl.2024.213.217
M. Xie, W.W. Lu, W. Yan, Y. C. Wei, Y. P. Chen, J. Xu
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Abstract

In this paper, a MoSe2/TiO2 composite photocatalyst was constructed by modifying TiO2 with MoSe2 as a group catalyst. The results showed that pure TiO2 and MoSe2 had no degradation activity for RhB, and the composite catalyst of 0.03 g MoSe2 had the best photocatalytic degradation activity for RhB. Through SEM, TEM, UV-VIS absorption spectrum, transient photocurrent curve, photoluminescence spectrum, and electrochemical impedance spectrum analysis, it can be seen that the excellent performance of 0.03 g MoSe2 composite sample is due to its excellent nanostructure, and uniform TiO2 nanosheets are attached to MoSe2 flower spheres. The active site of RhB photocatalytic degradation was increased, the visible light response and photobiological carrier separation were enhanced, and TiO2 had photocatalytic activity under simulated sunlight.
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花球中的 MoSe2 为 TiO2 光催化降解 RhB 提供了丰富的活性位点
本文以MoSe2为基团催化剂对TiO2进行改性,构建了MoSe2/TiO2复合光催化剂。结果表明,纯 TiO2 和 MoSe2 对 RhB 无降解活性,而 0.03 g MoSe2 的复合催化剂对 RhB 的光催化降解活性最好。通过扫描电镜、电子显微镜、紫外可见吸收光谱、瞬态光电流曲线、光致发光光谱和电化学阻抗谱分析可以看出,0.03 g MoSe2 复合样品的优异性能得益于其优异的纳米结构,均匀的 TiO2 纳米片附着在 MoSe2 花球上。增加了 RhB 光催化降解的活性位点,增强了可见光响应和光生物载体分离,TiO2 在模拟太阳光下具有光催化活性。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
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来源期刊
Accounts of Chemical Research
Accounts of Chemical Research 化学-化学综合
CiteScore
31.40
自引率
1.10%
发文量
312
审稿时长
2 months
期刊介绍: Accounts of Chemical Research presents short, concise and critical articles offering easy-to-read overviews of basic research and applications in all areas of chemistry and biochemistry. These short reviews focus on research from the author’s own laboratory and are designed to teach the reader about a research project. In addition, Accounts of Chemical Research publishes commentaries that give an informed opinion on a current research problem. Special Issues online are devoted to a single topic of unusual activity and significance. Accounts of Chemical Research replaces the traditional article abstract with an article "Conspectus." These entries synopsize the research affording the reader a closer look at the content and significance of an article. Through this provision of a more detailed description of the article contents, the Conspectus enhances the article's discoverability by search engines and the exposure for the research.
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