Impact of aluminum fluoride addition on crystallization, structure and thermal properties of lead borate glasses

Abstract

The glass composition (70-x)PbO–(30-y)B2O3–(x+y)AlF3, where x and y ranges from 0 to 20 mol%, were prepared using the conventional melt-quenching-annealing technique. The structural and thermal properties of the glasses were comprehensively analyzed using techniques like Differential Thermal Analysis (DTA), Dilatometry, Fourier-Transform Infrared Spectroscopy (FTIR), X-ray Diffraction (XRD), and Scanning Electron Microscopy (SEM). XRD confirmed the amorphous, non-crystalline structure of the glasses. The glass network was found to be composed of structural units such as PbO4, BO4, BO3 and AlO6 using FTIR spectroscopy. FTIR analysis revealed significant structural changes, including the transformation of BO4 to BO3 units and the increase in non-bridging bonds, particularly with higher AlF3 content. DTA was instrumental in determining characteristic temperatures, such as the glass transition, melting, and peak crystallization temperatures, along with glass stability parameters (∆T, Hr, Tgr) for all samples. The study found that the addition of AlF3 led to a decrease in these characteristic temperatures when replacing B2O3, but an increase when replacing PbO. Variations in the density and thermal expansion of the lead borate glass were observed upon the addition of AlF3, decreasing when substituting for PbO and increasing when substituting for B2O3. These findings provide insights into the properties of oxyfluoride glasses, paving the way for future optimization in their composition for varied applications.