Rheological Analysis on Hardening of Magnetorheological Grease with Kerosene

IF 17.7 1区 化学 Q1 CHEMISTRY, MULTIDISCIPLINARY Accounts of Chemical Research Pub Date : 2024-03-20 DOI:10.15282/ijame.21.1.2024.08.0854
Zheng Bin Pang, S. Mazlan, Mohd Aidy Faizal Johari, Muntaz Hana Ahmad Khairi
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Abstract

Magnetorheological grease (MRG) with dilution oils may suffer from reduced storage stability caused by oil separation. This phenomenon potentially causes a performance reduction of the material due to possible accelerated degradation of the grease medium. The long-term rheological behavior of MRG with kerosene (MRGK) was investigated in this study. MRGK was prepared with 10 wt% kerosene as the dilution oil, together with a sample of MRG without any kerosene as the control. A modular compact rheometer (MCR) was used to obtain rheological data from the MRG samples in an oscillatory strain sweep mode under the influence of magnetic fields, which ranged from 0A to 3A. After one year, the measurement was repeated to observe any changes to the rheology of MRG samples. Results showed a significant hardening of the sample diluted with kerosene, which mainly showed a drastic increase in off-state storage modulus at low strain. This was shown by the off-state storage modulus of MRGK, which after one year showed an increase of 15% in the initial storage modulus, and an increase of 2438% in the storage modulus at 10% strain. The MRG sample showed an increase of 50% and 47%, respectively. The on-state storage modulus did not appear to experience such a drastic change after one year. The study concluded that while dilution oil may be a promising candidate to reduce the initial viscosity of MRG, the resulting performance difference may compromise the long-term performance, and may even cause accelerated degradation when in use.
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用煤油硬化磁流变润滑脂的流变学分析
含有稀释油的磁流变润滑脂(MRG)可能会因油脂分离而降低储存稳定性。这种现象可能会导致润滑脂介质加速降解,从而降低材料的性能。本研究调查了含煤油的 MRG(MRGK)的长期流变行为。MRGK 以 10 wt% 的煤油作为稀释油,并以不含任何煤油的 MRG 样品作为对照。在 0A 至 3A 的磁场影响下,使用模块化紧凑型流变仪(MCR)以振荡应变扫描模式获取 MRG 样品的流变数据。一年后,重复测量以观察 MRG 样品流变学的任何变化。结果表明,用煤油稀释的样品出现了明显的硬化,主要表现为低应变时的离态存储模量急剧增加。这表现在 MRGK 的离态存储模量上,一年后,其初始存储模量增加了 15%,10% 应变时的存储模量增加了 2438%。MRG 样品分别增加了 50%和 47%。一年后,通态存储模量似乎没有发生如此剧烈的变化。研究得出的结论是,虽然稀释油可能是降低 MRG 初始粘度的一个有前途的候选方案,但由此产生的性能差异可能会影响长期性能,甚至可能导致使用中的加速降解。
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来源期刊
Accounts of Chemical Research
Accounts of Chemical Research 化学-化学综合
CiteScore
31.40
自引率
1.10%
发文量
312
审稿时长
2 months
期刊介绍: Accounts of Chemical Research presents short, concise and critical articles offering easy-to-read overviews of basic research and applications in all areas of chemistry and biochemistry. These short reviews focus on research from the author’s own laboratory and are designed to teach the reader about a research project. In addition, Accounts of Chemical Research publishes commentaries that give an informed opinion on a current research problem. Special Issues online are devoted to a single topic of unusual activity and significance. Accounts of Chemical Research replaces the traditional article abstract with an article "Conspectus." These entries synopsize the research affording the reader a closer look at the content and significance of an article. Through this provision of a more detailed description of the article contents, the Conspectus enhances the article's discoverability by search engines and the exposure for the research.
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