Alternative identification of wood from natural fallen trees of the Lecythidaceae family in the Central Amazonian using FT-NIR spectroscopy

IF 17.7 1区 化学 Q1 CHEMISTRY, MULTIDISCIPLINARY Accounts of Chemical Research Pub Date : 2024-03-01 DOI:10.1505/146554824838457844
C. Eugenio da Silva, C. Nascimento, J.A. Freitas, R. Araújo, F.M. Durgante, C. Zartman, C. Nascimento, N. Higuchi
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Abstract

The scientific identification of natural fallen trees in tropical forests is complex due to the lack of fertile material in field collection. The study evaluated the use of near-infrared spectroscopy with Fourier-transform (FT-NIR) in the discrimination of wood from fallen trees of the Lecythidaceae family. Seven trees were collected in the Central Amazonian region (Brazil), from which 63 specimens were prepared from the wood, and NIR spectra were obtained on different wood surfaces (total 756 spectra). Chemometric models were developed with a spectral data set, and the Mahalanobis algorithm was applied. The discriminant model with 2nd derivative spectra improved the identification capacity, resulting in errors < 5% in the identification of genus Couratari (3 ssp.), Eschweilera (2 ssp.), Holopyxidium (1 sp.) and Lecythis (1 sp.). The comparison of the spectral signatures of samples of fallen trees and wood library revealed that even when wood was exposed to environmental weathering, around 50% of the original bands were preserved, favouring discrimination at the genus level. The accuracy of the chemometric models developed indicates the applicability of FT-NIR spectroscopy integrative in identifying fallen trees from the Lecythidaceae family in the tropical forests.
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利用傅立叶变换近红外光谱法对亚马逊中部自然倒伏的鹅掌楸科树木的木材进行替代性鉴定
由于缺乏野外采集的可育材料,对热带森林中的天然倒伏树木进行科学鉴定非常复杂。本研究评估了傅立叶变换近红外光谱仪(FT-NIR)在鉴别落叶松科树木木材中的应用。研究人员在亚马逊中部地区(巴西)采集了 7 棵树,从中制备了 63 个木材标本,并在不同的木材表面获得了近红外光谱(共 756 个光谱)。利用光谱数据集开发了化学计量模型,并应用了 Mahalanobis 算法。带有二阶导数光谱的判别模型提高了识别能力,在识别 Couratari 属(3 种)、Eschweilera 属(2 种)、Holopyxidium 属(1 种)和 Lecythis 属(1 种)时误差小于 5%。对倒下的树木样本和木材库的光谱特征进行比较后发现,即使木材暴露在环境风化中,也能保留约 50%的原始条带,有利于在属一级进行鉴别。所建立的化学计量学模型的准确性表明,傅立叶变换近红外光谱综合技术适用于识别热带森林中的落叶松科树木。
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来源期刊
Accounts of Chemical Research
Accounts of Chemical Research 化学-化学综合
CiteScore
31.40
自引率
1.10%
发文量
312
审稿时长
2 months
期刊介绍: Accounts of Chemical Research presents short, concise and critical articles offering easy-to-read overviews of basic research and applications in all areas of chemistry and biochemistry. These short reviews focus on research from the author’s own laboratory and are designed to teach the reader about a research project. In addition, Accounts of Chemical Research publishes commentaries that give an informed opinion on a current research problem. Special Issues online are devoted to a single topic of unusual activity and significance. Accounts of Chemical Research replaces the traditional article abstract with an article "Conspectus." These entries synopsize the research affording the reader a closer look at the content and significance of an article. Through this provision of a more detailed description of the article contents, the Conspectus enhances the article's discoverability by search engines and the exposure for the research.
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