A New Method for Calculating the Hamaker Constant Based on the Hansen Solubility Parameters for Non-Polar Liquids

IF 4.7 Q2 MATERIALS SCIENCE, BIOMATERIALS ACS Applied Bio Materials Pub Date : 2024-02-22 DOI:10.3390/colloids8020014
H. Ohshima, Shin-ichi Takeda
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Abstract

A simple relationship between the Hamaker constant and the Hansen solubility parameters for non-polar liquids is derived by combining a Hamaker constant/surface tension relationship derived by Israelachvili and a Hansen solubility parameters/surface tension relationship derived by Abbott. With this relationship, one can easily estimate the Hamaker constant of non-polar liquids on the basis of the database of the Hansen solubility parameters. This is an entirely new method for calculating the Hamaker constant without recourse to data on the frequency-dependent dielectric permittivity of those substances (which are required for the rigorous Lifshitz theory) and laborious numerical calculations.
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根据非极性液体的汉森溶解度参数计算哈马克常数的新方法
通过结合 Israelachvili 提出的 Hamaker 常数/表面张力关系和 Abbott 提出的 Hansen 溶解度参数/表面张力关系,得出了非极性液体的 Hamaker 常数和 Hansen 溶解度参数之间的简单关系。有了这种关系,人们就可以根据汉森溶解度参数数据库轻松估算出非极性液体的 Hamaker 常数。这是一种计算 Hamaker 常数的全新方法,无需借助这些物质随频率变化的介电常数数据(严格的 Lifshitz 理论需要这些数据)和费力的数值计算。
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来源期刊
ACS Applied Bio Materials
ACS Applied Bio Materials Chemistry-Chemistry (all)
CiteScore
9.40
自引率
2.10%
发文量
464
期刊介绍: ACS Applied Bio Materials is an interdisciplinary journal publishing original research covering all aspects of biomaterials and biointerfaces including and beyond the traditional biosensing, biomedical and therapeutic applications. The journal is devoted to reports of new and original experimental and theoretical research of an applied nature that integrates knowledge in the areas of materials, engineering, physics, bioscience, and chemistry into important bio applications. The journal is specifically interested in work that addresses the relationship between structure and function and assesses the stability and degradation of materials under relevant environmental and biological conditions.
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