Vulcanization of styrene-butadiene rubber with the use of polysulfide sulfur-donors of controlled structure

IF 17.7 1区 化学 Q1 CHEMISTRY, MULTIDISCIPLINARY Accounts of Chemical Research Pub Date : 2024-01-01 DOI:10.5254/rct-d-23-00044
Jakub Wręczycki, D. Bieliński, T. Gozdek, Grzegorz Mlostoń
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Abstract

The sulfide polymers of variable and controlled sulfur content, obtained by anionic copolymerization of elemental sulfur and thiiranes (styrene sulfide and cyclohexene sulfide), were applied as curatives (sulfur donors) in the vulcanization process of styrene-butadiene rubber (SBR). The activity of polysulfides as curatives was investigated on the basis of rheometric measurements of the vulcanization process and calculations of curing parameters using kinetic data. The crosslink density and structure related to the mechanical properties of the vulcanizates under static and dynamic conditions were studied. The overall suitability of polysulfides as crosslinking agents for diene rubbers was investigated.
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使用结构可控的多硫化硫给体硫化丁苯橡胶
在丁苯橡胶(SBR)的硫化过程中,将元素硫和硫醚(苯乙烯硫醚和环己烯硫醚)阴离子共聚得到的硫含量可变且可控的硫化物聚合物用作硫化剂(硫供体)。根据硫化过程的流变测量结果和利用动力学数据计算的硫化参数,研究了多硫化物作为硫化剂的活性。研究了在静态和动态条件下与硫化胶机械性能相关的交联密度和结构。研究了聚硫化物作为二烯橡胶交联剂的整体适用性。
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来源期刊
Accounts of Chemical Research
Accounts of Chemical Research 化学-化学综合
CiteScore
31.40
自引率
1.10%
发文量
312
审稿时长
2 months
期刊介绍: Accounts of Chemical Research presents short, concise and critical articles offering easy-to-read overviews of basic research and applications in all areas of chemistry and biochemistry. These short reviews focus on research from the author’s own laboratory and are designed to teach the reader about a research project. In addition, Accounts of Chemical Research publishes commentaries that give an informed opinion on a current research problem. Special Issues online are devoted to a single topic of unusual activity and significance. Accounts of Chemical Research replaces the traditional article abstract with an article "Conspectus." These entries synopsize the research affording the reader a closer look at the content and significance of an article. Through this provision of a more detailed description of the article contents, the Conspectus enhances the article's discoverability by search engines and the exposure for the research.
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