Recent advances of ring opening of epoxidation of palm oil derived from oleic acid via in situ hydrolysis under moderate temperature

IF 17.7 1区 化学 Q1 CHEMISTRY, MULTIDISCIPLINARY Accounts of Chemical Research Pub Date : 2024-02-13 DOI:10.1002/vjch.202300135
Mohamad Zarqani Yeop, I. S. Azmi, Siti Juwairiyah A. Rahman, M. Jalil, Izni Mariah Ibrahim
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Abstract

Epoxidized oleic acid was considered a more sustainable alternative to traditional plasticizers such as phthalates, which have been linked to potential health and environmental hazards. This study aims to synthesize and characterize the formation of dihydroxystearic acid (DHSA) from the ring opening of epoxidized oleic acid. The optimal reaction parameters to produce DHSA were found using sulfuric acid as catalyst in which the maximum relative conversion was reached up to 86%. The detection of hydroxyl group was using Fourier Transform Infrared Spectroscopy. Then, a mathematical model was developed using MATLAB software, and as a result the kinetic model provided a good description of the reaction process, and it could be used to predict the behavior of the reaction under different conditions. Overall, the optimal reaction conditions and the maximum relative conversion of palm oleic acid to oxirane, are important contributions to the field of green chemistry.
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通过适温原位水解实现油酸棕榈油环氧化开环的最新进展
环氧化油酸被认为是邻苯二甲酸盐等传统增塑剂的一种更具可持续性的替代品,而邻苯二甲酸盐与潜在的健康和环境危害有关。本研究旨在合成环氧化油酸开环生成的二羟基硬脂酸(DHSA)并描述其特性。以硫酸为催化剂,找到了生成 DHSA 的最佳反应参数,其最大相对转化率可达 86%。羟基的检测采用傅立叶变换红外光谱法。然后,使用 MATLAB 软件建立了数学模型,结果动力学模型很好地描述了反应过程,并可用于预测不同条件下的反应行为。总之,最佳反应条件和棕榈油酸到环氧乙烷的最大相对转化率是对绿色化学领域的重要贡献。
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来源期刊
Accounts of Chemical Research
Accounts of Chemical Research 化学-化学综合
CiteScore
31.40
自引率
1.10%
发文量
312
审稿时长
2 months
期刊介绍: Accounts of Chemical Research presents short, concise and critical articles offering easy-to-read overviews of basic research and applications in all areas of chemistry and biochemistry. These short reviews focus on research from the author’s own laboratory and are designed to teach the reader about a research project. In addition, Accounts of Chemical Research publishes commentaries that give an informed opinion on a current research problem. Special Issues online are devoted to a single topic of unusual activity and significance. Accounts of Chemical Research replaces the traditional article abstract with an article "Conspectus." These entries synopsize the research affording the reader a closer look at the content and significance of an article. Through this provision of a more detailed description of the article contents, the Conspectus enhances the article's discoverability by search engines and the exposure for the research.
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