Effect of surface modification of metal powders (by aluminum stearate) on the properties of metal injection molding feedstock

IF 17.7 1区 化学 Q1 CHEMISTRY, MULTIDISCIPLINARY Accounts of Chemical Research Pub Date : 2024-01-31 DOI:10.1177/00325899231212626
Haihong Ma, Shuncheng Fang, Zhengfa Zhou, F. Ren, Weibing Xu, Guoming Chen
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Abstract

Metal injection molding (MIM) is a net-forming technology for manufacturing miniature metal parts, which can improve the manufacturing accuracy of complex-shaped parts. In this study, aluminum stearate was used to modify the 17-4PH stainless steel powder, the binder was composed of (PMMA) and (PEG) with the volume ratio of 7:3. The effects of aluminum stearate surfactant amount on the feedstock viscosity, water debinding rate and thermal debinding shape were studied. The results showed that the coating of aluminum stearate breaks the agglomeration between the powders and decreases the viscosity of the feedstock. When the addition of aluminum stearate was 0.6wt% of the powder mass, the melt index, density and flexural modulus of the feedstock were 81.5 g/10 min, 5.44 g/cm3, and 1643Mpa, respectively, and the thermal debinding shape retention was the best of all debinded parts. However, too much aluminum stearate makes the feedstocks thicker and the green part weaker.
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金属粉末表面改性(硬脂酸铝)对金属注射成型原料性能的影响
金属注射成型(MIM)是一种制造微型金属零件的净成形技术,可提高复杂形状零件的制造精度。本研究采用硬脂酸铝对 17-4PH 不锈钢粉末进行改性,粘合剂由(PMMA)和(PEG)组成,体积比为 7:3。研究了硬脂酸铝表面活性剂用量对原料粘度、水脱粘率和热脱粘形状的影响。研究结果表明,硬脂酸铝的涂覆可以打破粉末之间的团聚,降低原料的粘度。当硬脂酸铝的添加量为粉末质量的 0.6wt% 时,原料的熔融指数、密度和弯曲模量分别为 81.5 g/10min、5.44 g/cm3 和 1643Mpa,热脱胶形状保持率是所有脱胶部件中最好的。然而,过多的硬脂酸铝会使原料变厚,绿色部件变弱。
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阿拉丁
polyethylene glycol (PEG)
阿拉丁
polymethyl methacrylate (PMMA)
来源期刊
Accounts of Chemical Research
Accounts of Chemical Research 化学-化学综合
CiteScore
31.40
自引率
1.10%
发文量
312
审稿时长
2 months
期刊介绍: Accounts of Chemical Research presents short, concise and critical articles offering easy-to-read overviews of basic research and applications in all areas of chemistry and biochemistry. These short reviews focus on research from the author’s own laboratory and are designed to teach the reader about a research project. In addition, Accounts of Chemical Research publishes commentaries that give an informed opinion on a current research problem. Special Issues online are devoted to a single topic of unusual activity and significance. Accounts of Chemical Research replaces the traditional article abstract with an article "Conspectus." These entries synopsize the research affording the reader a closer look at the content and significance of an article. Through this provision of a more detailed description of the article contents, the Conspectus enhances the article's discoverability by search engines and the exposure for the research.
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