Optimization of Reaction Conducting Efficiency by using the Potential of Column Catalytic Reactor

Katsman E
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Abstract

The paper intends for art of running heterogeneous-catalytic chemical reactions with high efficiency using column catalytic reactor with fixed catalyst layer. Described are potential possibilities of this undervalued apparatus to satisfy conditions for selective running of first step in multistep irreversible or reversible reactions in liquid-gas/vapor flow. Minor changes of working regime and construction of the apparatus discussed with the aim to increase the indexes. The idea of these changes is to suppress side reaction steps using due space localization and segregation of reaction participants. As a result, the needed reagents only have possibility for good contact with catalyst and each other. These features may straightly relate to reactionrectification, but realizes much cheaper. The examples chosen for demonstration are Ipatieff’s alkylation of benzene with propylene on “solid acid” and so called “selective hydrogenation” of acetylenes and conjugated dienes.
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利用柱式催化反应器的潜能优化反应传导效率
本文旨在介绍使用带有固定催化剂层的柱式催化反应器高效运行异相催化化学反应的技术。本文阐述了这种价值被低估的设备的潜在可能性,以满足在液-气-气流中选择性运行多步不可逆或可逆反应第一步的条件。讨论了工作制度和设备结构的细微变化,目的是提高指标。这些改变的目的是利用反应参与者的空间定位和隔离来抑制副反应步骤。因此,所需的试剂只能与催化剂和其他试剂进行良好的接触。这些特点可能与反应矫正直接相关,但实现起来要便宜得多。用于演示的实例包括伊帕蒂耶夫的苯与丙烯在 "固体酸 "上的烷基化反应,以及乙炔和共轭二烯的所谓 "选择性氢化 "反应。
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