Assessment of Some Toxic Heavy Metals in Rice and Beans Sold in Benin City, Nigeria

O.B. Ovonramwen, C.F. Awulor, J.E. Ukpebor, E. Ukpebor
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Abstract

Rice and beans are staple foods for more than 50% of the world's population. They are prone to heavy metal contamination, with the  global rise in heavy metal pollution, which causes harm and danger to the ecosystem and puts people and other living things in major  health problems. This study aimed to determine the level of some heavy metals in local and foreign rice and white and brown bean  samples obtained from an open market in Benin City. The samples were prepared and analysed using a standard method with the aid of  an atomic absorption spectrophotometer (A.A.S.). The results of the analysis show the levels of heavy metals in the beans and rice ranged  from 0.013–0.067 mg/kg for Pb, 0.02-0.043 mg/kg for Cr, 0.003-0.367 mg/kg for Mn, 0.263–1.017 mg/kg for Zn, 0.30–0.933 mg/kg  for Fe, and 0.01–0.023 mg/kg for Cu, with Cd being the only metal below the detection limit. Statistical analysis using a t-test showed that  there was no significant difference between the levels of the selected heavy metals analysed among the bean samples and those  analysed among the rice samples. If these heavy metals are used as benchmarks for measuring the product's quality, local rice would be  considered to be of higher quality than foreign rice, according to statistical analysis using a correlation matrix that showed a nearly  identical heavy metal composition between local and foreign rice. The concentration of all the metals studied was observed to be present  at tolerable levels lower than the maximum permissible limit as given by the World Health Organisation (WHO). Based on the research  findings, the rice and bean samples studied were safe for human consumption.        
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对尼日利亚贝宁市销售的大米和豆类中某些有毒重金属的评估
大米和豆类是世界上 50%以上人口的主食。随着全球重金属污染的加剧,它们很容易受到重金属污染,对生态系统造成危害和危害,使人类和其他生物面临重大健康问题。本研究旨在确定从贝宁市公开市场获得的本地和外国大米以及白豆和糙豆样本中某些重金属的含量。样品采用标准方法制备,并借助原子吸收分光光度计(A.A.S.)进行分析。分析结果显示,豆类和大米中的重金属含量为:铅 0.013-0.067 毫克/千克、铬 0.02-0.043 毫克/千克、锰 0.003-0.367 毫克/千克、锌 0.263-1.017 毫克/千克、铁 0.30-0.933 毫克/千克、铜 0.01-0.023 毫克/千克,其中镉是唯一低于检测限的金属。使用 t 检验法进行的统计分析显示,豆类样本中分析出的选定重金属含量与大米样本中分析出的重金属含量没有明显差异。如果把这些重金属作为衡量产品质量的基准,那么根据相关矩阵的统计分析,本地大米和外国大米的重金属成分几乎完全相同,因此本地大米的质量要高于外国大米。据观察,所研究的所有金属浓度都低于世界卫生组织(WHO)规定的最高允许限值。根据研究结果,所研究的大米和豆类样品可供人类安全食用。
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