Spectral-Luminescence Properties of ZrO2–Sc2O3–Tb2O3 Crystals

IF 0.8 4区 物理与天体物理 Q4 OPTICS Optics and Spectroscopy Pub Date : 2024-04-01 DOI:10.1134/S0030400X23100016
S. Kh. Batygov, M. A. Borik, A. V. Kulebyakin, N. A. Larina, E. E. Lomonova, V. A. Myzina, P. A. Ryabochkina, N. V. Sidorova, A. D. Taratynova, N. Yu. Tabachkova
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Abstract

Crystals of the concentration series ZrO2–(8–10) mol % Sc2O3–(1–2) mol % Tb2O3 were grown by the method of directional crystallization of the melt from a cold container. Analysis of the spectral-luminescence characteristics of these crystals after growth and after annealing processing in a vacuum revealed the presence of both Tb3+ and Tb4+ ions in them. In crystals ZrO2–(8–10) mol % Sc2O3–(1–2) mol % Tb2O3, the presence of a process of non-radiative energy transfer from Tb4+ ions to Tb3+ ions was revealed.

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ZrO2-Sc2O3-Tb2O3 晶体的光谱-发光特性
摘要 通过冷容器熔体定向结晶法,生长出了 ZrO2-(8-10) mol % Sc2O3-(1-2) mol % Tb2O3 浓度系列晶体。对这些晶体生长后和在真空中退火处理后的光谱-发光特性分析表明,其中同时存在 Tb3+ 和 Tb4+ 离子。在 ZrO2-(8-10) mol % Sc2O3-(1-2) mol % Tb2O3 晶体中,发现了从 Tb4+ 离子到 Tb3+ 离子的非辐射能量转移过程。
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来源期刊
Optics and Spectroscopy
Optics and Spectroscopy 物理-光谱学
CiteScore
1.60
自引率
0.00%
发文量
55
审稿时长
4.5 months
期刊介绍: Optics and Spectroscopy (Optika i spektroskopiya), founded in 1956, presents original and review papers in various fields of modern optics and spectroscopy in the entire wavelength range from radio waves to X-rays. Topics covered include problems of theoretical and experimental spectroscopy of atoms, molecules, and condensed state, lasers and the interaction of laser radiation with matter, physical and geometrical optics, holography, and physical principles of optical instrument making.
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