Towards Routine 7Li In Situ Solid-State NMR Studies of Electrochemical Processes in Li|LiPF6|LFP Cells

IF 1.1 4区 物理与天体物理 Q4 PHYSICS, ATOMIC, MOLECULAR & CHEMICAL Applied Magnetic Resonance Pub Date : 2024-04-11 DOI:10.1007/s00723-024-01643-1
Edina Šić, Dominion Fredericks, Oliver Pecher, Sebastian Wegner, Hergen Breitzke, Vickram Singh, Gerd Buntkowsky, Torsten Gutmann
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Abstract

In this study, electrochemical processes in a Li|LiPF6|LFP cell have been explored applying advanced solid-state NMR technologies. In situ solid-state NMR allows to monitor structural changes in local environments in commercially available cell components during galvanostatic cycling. In collaboration with Dragonfly Energy, ePROBE GmbH and Bruker BioSpin GmbH & Co. KG, we have demonstrated an experimental procedure for routine application of in situ solid-state NMR for battery research. This points out the high potential of this approach for use in the energy storage industry.

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对 Li|LiPF6|LFP 电池中的电化学过程进行常规 7Li 原位固态 NMR 研究
本研究采用先进的固态核磁共振技术探索了 Li|LiPF6|LFP 电池中的电化学过程。原位固态 NMR 可以监测市售电池组件在电静力循环过程中局部环境的结构变化。我们与 Dragonfly Energy、ePROBE GmbH 和 Bruker BioSpin GmbH & Co.KG 合作,我们展示了将原位固态 NMR 常规应用于电池研究的实验程序。这表明这种方法在储能行业的应用潜力巨大。
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来源期刊
Applied Magnetic Resonance
Applied Magnetic Resonance 物理-光谱学
CiteScore
1.90
自引率
10.00%
发文量
59
审稿时长
2.3 months
期刊介绍: Applied Magnetic Resonance provides an international forum for the application of magnetic resonance in physics, chemistry, biology, medicine, geochemistry, ecology, engineering, and related fields. The contents include articles with a strong emphasis on new applications, and on new experimental methods. Additional features include book reviews and Letters to the Editor.
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