The Controlled Synthesis of Flower-Like TiO2 Nanosheets with Enhanced Photocatalytic Performance

IF 2.7 4区 化学 Q2 CHEMISTRY, INORGANIC & NUCLEAR Journal of Cluster Science Pub Date : 2024-04-06 DOI:10.1007/s10876-024-02599-9
{"title":"The Controlled Synthesis of Flower-Like TiO2 Nanosheets with Enhanced Photocatalytic Performance","authors":"","doi":"10.1007/s10876-024-02599-9","DOIUrl":null,"url":null,"abstract":"<h3>Abstract</h3> <p>Exploring inorganic flower-like nanosheets is of increasing interest not only for fundamental research, but also for development of devices due to their good chemical stability, versatility, and high surface-to-volume ratio. In this work, flower-like TiO<sub>2</sub> nanosheets (FTN) are successfully synthesized by a facile hydrothermal method. Notably, a series of single-factor experiments are carried out to drive multiple functional components in order to integrate into a single flower-like nanostructure perfectly. In addition, these experimental results further reveal that alcohol/glycerol molar ratio acts in a vital role for preparing optimal flower-like morphology and structure of TiO<sub>2</sub>. Furthermore, the photodegradation pathways and mechanism of Levofloxacin (LVOF) by FTN are shown according to photodegradation intermediates of LVOF, trapping experiments, and ligand-to-metal charge transfer (LMCT) sensitizing effect. Therefore, the present work not only demonstrates the controlled synthesis of flower-like TiO<sub>2</sub> nanosheets, but also provides a guide for constructing other inorganic flower-like nanosheets or TiO<sub>2</sub>-based photocatalysts with optimal morphology, structure and photocatalytic performance.</p>","PeriodicalId":618,"journal":{"name":"Journal of Cluster Science","volume":null,"pages":null},"PeriodicalIF":2.7000,"publicationDate":"2024-04-06","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Journal of Cluster Science","FirstCategoryId":"92","ListUrlMain":"https://doi.org/10.1007/s10876-024-02599-9","RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q2","JCRName":"CHEMISTRY, INORGANIC & NUCLEAR","Score":null,"Total":0}
引用次数: 0

Abstract

Exploring inorganic flower-like nanosheets is of increasing interest not only for fundamental research, but also for development of devices due to their good chemical stability, versatility, and high surface-to-volume ratio. In this work, flower-like TiO2 nanosheets (FTN) are successfully synthesized by a facile hydrothermal method. Notably, a series of single-factor experiments are carried out to drive multiple functional components in order to integrate into a single flower-like nanostructure perfectly. In addition, these experimental results further reveal that alcohol/glycerol molar ratio acts in a vital role for preparing optimal flower-like morphology and structure of TiO2. Furthermore, the photodegradation pathways and mechanism of Levofloxacin (LVOF) by FTN are shown according to photodegradation intermediates of LVOF, trapping experiments, and ligand-to-metal charge transfer (LMCT) sensitizing effect. Therefore, the present work not only demonstrates the controlled synthesis of flower-like TiO2 nanosheets, but also provides a guide for constructing other inorganic flower-like nanosheets or TiO2-based photocatalysts with optimal morphology, structure and photocatalytic performance.

查看原文
分享 分享
微信好友 朋友圈 QQ好友 复制链接
本刊更多论文
可控合成具有增强光催化性能的花朵状二氧化钛纳米片
摘要 由于无机花状纳米片具有良好的化学稳定性、多功能性和高比表面体积比,因此探索无机花状纳米片不仅在基础研究方面,而且在器件开发方面也越来越受到关注。本研究采用水热法成功合成了花状二氧化钛纳米片(FTN)。值得注意的是,该研究进行了一系列单因素实验,以驱动多种功能成分完美地集成到单个花状纳米结构中。此外,这些实验结果进一步揭示了酒精/甘油摩尔比在制备最佳花状形态和结构的二氧化钛中起着至关重要的作用。此外,根据左氧氟沙星(LVOF)的光降解中间产物、捕集实验和配体对金属电荷转移(LMCT)的敏化效应,展示了 FTN 对左氧氟沙星(LVOF)的光降解途径和机理。因此,本研究不仅证明了花状 TiO2 纳米片的可控合成,而且为构建其他具有最佳形态、结构和光催化性能的无机花状纳米片或基于 TiO2 的光催化剂提供了指导。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
求助全文
约1分钟内获得全文 去求助
来源期刊
Journal of Cluster Science
Journal of Cluster Science 化学-无机化学与核化学
CiteScore
6.70
自引率
0.00%
发文量
166
审稿时长
3 months
期刊介绍: The journal publishes the following types of papers: (a) original and important research; (b) authoritative comprehensive reviews or short overviews of topics of current interest; (c) brief but urgent communications on new significant research; and (d) commentaries intended to foster the exchange of innovative or provocative ideas, and to encourage dialogue, amongst researchers working in different cluster disciplines.
期刊最新文献
Design of a High-Performance WO3/g-C3N4 Z-Scheme Photocatalyst for Effective Phenol Degradation and Antibacterial Activity Advancing Autonomous Nanomedicine: Bridging the Gap from Concept to Potential Clinical Studies Theoretical Prediction of the Smallest Sized Tricyclic-Boron Oxide B6O62+ Fluorescent Nanoprobe Utilizing Tryptophan-Functionalized Silver Nanoclusters for Enhanced Gemcitabine Detection: Optimization and Application in Real Samples Enhanced Wound Healing Activity in Animal Model via Developing and Designing of Self-nano Emulsifying Drug Delivery System (SNEDDS) for the Co-delivery of Hesperidin and Rutin
×
引用
GB/T 7714-2015
复制
MLA
复制
APA
复制
导出至
BibTeX EndNote RefMan NoteFirst NoteExpress
×
×
提示
您的信息不完整,为了账户安全,请先补充。
现在去补充
×
提示
您因"违规操作"
具体请查看互助需知
我知道了
×
提示
现在去查看 取消
×
提示
确定
0
微信
客服QQ
Book学术公众号 扫码关注我们
反馈
×
意见反馈
请填写您的意见或建议
请填写您的手机或邮箱
已复制链接
已复制链接
快去分享给好友吧!
我知道了
×
扫码分享
扫码分享
Book学术官方微信
Book学术文献互助
Book学术文献互助群
群 号:481959085
Book学术
文献互助 智能选刊 最新文献 互助须知 联系我们:info@booksci.cn
Book学术提供免费学术资源搜索服务,方便国内外学者检索中英文文献。致力于提供最便捷和优质的服务体验。
Copyright © 2023 Book学术 All rights reserved.
ghs 京公网安备 11010802042870号 京ICP备2023020795号-1