Removal of Anionic Methyl Orange Dye from Water by Poly[2-methyl-1H-indole] Derivatives: Investigation of Kinetics and Isotherms of Adsorption

Abstract

The adsorption properties toward methyl orange (MO) were evaluated for poly[2-methyl-1H-indole] and its derivatives. The influence of pH, ionic strength of solution, composition, and amount of sorbent on the adsorption of MO dye was investigated; the kinetics of dye adsorption was studied. The adsorption isotherms were analyzed using different models of sorption equilibrium. The presence of chemical interaction between polyindoles and dye was proved by IR and UV spectroscopy methods. The sorption of MO with polymers is realized mainly due to the formation of electrostatic interactions between the sulfogroup of the dye and the imino group of the sorbent. Microphotographs demonstrate the change in the morphology of polyindoles after adsorption, which further confirms the structural changes in the polymers. It was found that the main factors affecting the sorption capacity of the studied materials are the position and nature of substituents in the polymers and the sorption conditions. For example, polyindoles containing a methoxy group in their structure (o-OMePIn and m-OMePIn) have the best sorption activity. These polymers are effective in adsorbing dyes, which means that they can be used in wastewater treatment.