Microstructure Features of Yttrium Orthoferrite Thin Films on Sapphire

IF 1.1 4区 材料科学 Q3 METALLURGY & METALLURGICAL ENGINEERING Physics of Metals and Metallography Pub Date : 2024-04-21 DOI:10.1134/s0031918x23602287
A. L. Vasiliev, I. A. Subbotin, A. O. Belyaeva, Yu. M. Chesnokov, V. V. Izyurov, K. A. Merentsova, M. S. Artemiev, S. S. Dubinin, A. P. Nosov, E. M. Pashaev
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Abstract

X-ray diffraction and electron microscopy were used to examine the crystal structure features of ultrathin (3–50 nm) yttrium orthoferrite films, obtained by magnetron sputtering of stoichiometric composition target on α-Al2O3 substrates with orientation. The morphology and crystal structure of the films differ significantly depending on their thickness. In the thinnest films, several phases are formed, including yttrium orthoferrite with an orthorhombic crystal lattice (o-YFeO3), yttrium hexaferrite with a hexagonal crystal lattice (h-YFeO3), iron-yttrium garnet (Y3Fe5O12), and iron oxides such as hematite and maghemite. The study examines the local composition and determines the orientation ratios between the crystallized phases and the substrate. The films with a thickness greater than 10 nm predominantly exhibit a highly textured phase of o-YFeO3 with a small admixture of iron-yttrium garnet.

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蓝宝石上正铁钇薄膜的微观结构特征
摘要 利用 X 射线衍射和电子显微镜研究了超薄(3-50 nm)正铁氧体钇薄膜的晶体结构特征,这些薄膜是用磁控溅射方法在具有取向性的α-Al2O3 基质上获得的。薄膜的形态和晶体结构因厚度不同而有很大差异。在最薄的薄膜中,形成了几种相,包括正方晶格的正铁钇(o-YFeO3)、六方晶格的六铁钇(h-YFeO3)、铁钇石榴石(Y3Fe5O12)以及赤铁矿和磁铁矿等铁氧化物。研究对局部成分进行了检测,并确定了结晶相与基底之间的取向比。厚度大于 10 nm 的薄膜主要呈现出 o-YFeO3 的高纹理相,其中掺杂少量铁钇榴石。
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来源期刊
Physics of Metals and Metallography
Physics of Metals and Metallography 工程技术-冶金工程
CiteScore
2.00
自引率
25.00%
发文量
108
审稿时长
3 months
期刊介绍: The Physics of Metals and Metallography (Fizika metallov i metallovedenie) was founded in 1955 by the USSR Academy of Sciences. Its scientific profile involves the theory of metals and metal alloys, their electrical and magnetic properties, as well as their structure, phase transformations, and principal mechanical properties. The journal also publishes scientific reviews and papers written by experts involved in fundamental, application, and technological studies. The annual volume of publications amounts to some 250 papers submitted from 100 leading national scientific institutions.
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