Removal of Simazine from Aqueous Environment through Polymeric Membrane System

IF 0.5 4区 化学 Q4 CHEMISTRY, ANALYTICAL Journal of Water Chemistry and Technology Pub Date : 2024-04-21 DOI:10.3103/S1063455X24020036
Duygu Ataman, Canan Onac, Ahmet Kaya, Hamza Korkmaz Alpoguz
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Abstract

In this study, the kinetic transport of the simazine herbicide, which creates a serious threat to human health, was realized based on the diffusion via polymer inclusion membrane. In the polymer inclusion membrane synthesis, Aliquat 336 was used as a synthetic carrier and 2-nitrophenyl octyl ether was used as a plasticizer. The effect of the carrier concentration, the effect of the donor phase acid on the transport efficiency and the effect of the acceptor phase type change on the parameters of transport efficiency were studied. 62.56% of simazine was removed from donor phase at the end of 48 h in the optimum experimental conditions and permeability; flux values were calculated to be 3.056 × 10–7 m/s and 1.515 × 10–7 mol/m2s, respectively. As the last step, the surface characterizations of the polymer inclusion membranes were clarified using the method of field emission scanning electron microscopy. This study demonstrated economically and environmentally sustainable processes for the removal of micropollutants such as simazine.

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通过聚合物膜系统去除水环境中的西玛津
摘要 本研究基于聚合物包涵膜的扩散作用,实现了严重危害人类健康的西玛津除草剂的动力学迁移。在聚合物包涵膜的合成过程中,采用烯草酮 336 作为合成载体,2-硝基苯辛基醚作为增塑剂。研究了载体浓度、供体相酸对迁移效率的影响以及受体相类型变化对迁移效率参数的影响。在最佳实验条件和渗透率下,48 小时结束时,供体相中 62.56% 的西玛津被清除;计算得出的通量值分别为 3.056 × 10-7 m/s 和 1.515 × 10-7 mol/m2s。最后,利用场发射扫描电子显微镜方法阐明了聚合物包合物膜的表面特征。这项研究展示了去除西玛津等微污染物的经济和环境可持续工艺。
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来源期刊
Journal of Water Chemistry and Technology
Journal of Water Chemistry and Technology CHEMISTRY, APPLIED-CHEMISTRY, ANALYTICAL
自引率
0.00%
发文量
51
审稿时长
>12 weeks
期刊介绍: Journal of Water Chemistry and Technology focuses on water and wastewater treatment, water pollution monitoring, water purification, and similar topics. The journal publishes original scientific theoretical and experimental articles in the following sections: new developments in the science of water; theoretical principles of water treatment and technology; physical chemistry of water treatment processes; analytical water chemistry; analysis of natural and waste waters; water treatment technology and demineralization of water; biological methods of water treatment; and also solicited critical reviews summarizing the latest findings. The journal welcomes manuscripts from all countries in the English or Ukrainian language. All manuscripts are peer-reviewed.
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