In biased and soft-walled channels: Insights into transport phenomena and damped modulation.

Wenyue Fan, Meng Hu, Lukun Feng, Xiao Luo, Yao Lu, Jing-Dong Bao
{"title":"In biased and soft-walled channels: Insights into transport phenomena and damped modulation.","authors":"Wenyue Fan, Meng Hu, Lukun Feng, Xiao Luo, Yao Lu, Jing-Dong Bao","doi":"10.1063/5.0195202","DOIUrl":null,"url":null,"abstract":"The motion of a particle along a channel of finite width is known to be affected by either the presence of energy barriers or changes in the bias forces along the channel direction. By using the lateral equilibrium hypothesis, we have successfully derived the effective diffusion coefficient for soft-walled channels, and the diffusion is found to be influenced by the curvature profile of the potential. A typical phenomenon of diffusion enhancement is observed under the appropriate parameter conditions. We first discovered an anomalous phenomenon of quasi-periodic enhancement of oscillations, which cannot be captured by the one-dimensional effective potential, under the combination of sub-Ohmic damping with two-dimensional restricted channels. We innovatively develop the effective potential and the formation mechanism of velocity variance under super-Ohmic and ballistic damping, and meanwhile, ergodicity is of concern. The theoretical framework of a ballistic system can be reinterpreted through the folding acceleration theory. This comprehensive analysis significantly enhances our understanding of diffusion processes in constrained geometries.","PeriodicalId":501648,"journal":{"name":"The Journal of Chemical Physics","volume":"26 8","pages":""},"PeriodicalIF":0.0000,"publicationDate":"2024-04-25","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"The Journal of Chemical Physics","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.1063/5.0195202","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
引用次数: 0

Abstract

The motion of a particle along a channel of finite width is known to be affected by either the presence of energy barriers or changes in the bias forces along the channel direction. By using the lateral equilibrium hypothesis, we have successfully derived the effective diffusion coefficient for soft-walled channels, and the diffusion is found to be influenced by the curvature profile of the potential. A typical phenomenon of diffusion enhancement is observed under the appropriate parameter conditions. We first discovered an anomalous phenomenon of quasi-periodic enhancement of oscillations, which cannot be captured by the one-dimensional effective potential, under the combination of sub-Ohmic damping with two-dimensional restricted channels. We innovatively develop the effective potential and the formation mechanism of velocity variance under super-Ohmic and ballistic damping, and meanwhile, ergodicity is of concern. The theoretical framework of a ballistic system can be reinterpreted through the folding acceleration theory. This comprehensive analysis significantly enhances our understanding of diffusion processes in constrained geometries.
查看原文
分享 分享
微信好友 朋友圈 QQ好友 复制链接
本刊更多论文
在偏压和软壁通道中:对传输现象和阻尼调制的见解。
众所周知,粒子沿有限宽度通道的运动会受到通道方向存在的能量障碍或偏向力变化的影响。通过使用横向平衡假说,我们成功地推导出了软壁通道的有效扩散系数,并发现扩散受势能曲率曲线的影响。在适当的参数条件下,可以观察到典型的扩散增强现象。我们首次发现了在亚欧姆阻尼与二维受限通道相结合的情况下,振荡的准周期增强这一反常现象,而一维有效势无法捕捉这一现象。我们创新性地发展了超欧姆阻尼和弹道阻尼下的有效势和速度方差的形成机制,同时关注了遍历性。弹道系统的理论框架可以通过折叠加速理论重新解释。这种全面的分析极大地增强了我们对受约束几何中扩散过程的理解。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
求助全文
约1分钟内获得全文 去求助
来源期刊
自引率
0.00%
发文量
0
期刊最新文献
Substitutional Cu doping at the cation sites in Ba2YNbO6 toward improved visible-light photoactivity—A first-principles HSE06 study GW with hybrid functionals for large molecular systems Classical and quantum thermodynamics in a non-equilibrium regime: Application to thermostatic Stirling engine Thermodynamic quantum Fokker–Planck equations and their application to thermostatic Stirling engine The “simple” photochemistry of thiophene
×
引用
GB/T 7714-2015
复制
MLA
复制
APA
复制
导出至
BibTeX EndNote RefMan NoteFirst NoteExpress
×
×
提示
您的信息不完整,为了账户安全,请先补充。
现在去补充
×
提示
您因"违规操作"
具体请查看互助需知
我知道了
×
提示
现在去查看 取消
×
提示
确定
0
微信
客服QQ
Book学术公众号 扫码关注我们
反馈
×
意见反馈
请填写您的意见或建议
请填写您的手机或邮箱
已复制链接
已复制链接
快去分享给好友吧!
我知道了
×
扫码分享
扫码分享
Book学术官方微信
Book学术文献互助
Book学术文献互助群
群 号:481959085
Book学术
文献互助 智能选刊 最新文献 互助须知 联系我们:info@booksci.cn
Book学术提供免费学术资源搜索服务,方便国内外学者检索中英文文献。致力于提供最便捷和优质的服务体验。
Copyright © 2023 Book学术 All rights reserved.
ghs 京公网安备 11010802042870号 京ICP备2023020795号-1