Synthesis and Fabrication of Luminescence of CsPbBr3/PAN Nanocomposite Fiber

Taras Genovievo De Yonarosa, A. D. Pramata, Farhan Aryo Hutomo, Diah Susanti
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Abstract

Perovskite semiconductor have gained increasing attention in the recent years. However, pristine halide perovskites often faces bottle-neck related to low their stability. Herein, for the first time synthesis and fabrication of CsPbBr3/PAN fiber composite with electrospinning method is reported. CsPbBr3 quantum dots (QDs) embedded PAN fiber were successfully fabricated based on the XRD and FTIR test result. The result demonstrates electrospun fiber stable for over than one week in the condition of being immersed in water. The CsPbBr3 QDs was synthesized by Ligand Assisted Reprecipitation Process (LARP) method. The average particle size of our CsPbBr3 particle sizes ranging from 80 to 240 nm. Our findings reveal that the effect of variations between toluene and acetone had an effect on the size of the fiber and the intensity of photoluminescence reduction of the CsPbBr3/PAN fiber composite. Which is the smallest fiber and the lowest reduction intensity belongs to the 4:1 variation, namely with a fiber size of a 727.56 nm and a percentage decrease in intensity of 66,67%.
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铯硼砂/PAN 纳米复合纤维的合成与发光制备
近年来,过氧化物半导体越来越受到人们的关注。然而,原始的卤化物包晶往往面临着稳定性低的瓶颈。本文首次报道了电纺丝法合成和制备 CsPbBr3/PAN 纤维复合材料。根据 XRD 和 FTIR 测试结果,成功制备了嵌入 CsPbBr3 量子点(QDs)的 PAN 纤维。结果表明,电纺纤维在水中浸泡一周以上仍保持稳定。CsPbBr3 QDs 是通过配体辅助沉淀法(LARP)合成的。CsPbBr3 的平均粒径为 80 至 240 nm。我们的研究结果表明,甲苯和丙酮之间的变化对 CsPbBr3/PAN 纤维复合材料的纤维尺寸和光致发光还原强度有影响。其中,4:1 变化的纤维最小,还原强度最低,即纤维尺寸为 727.56 nm,强度下降了 66.67%。
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