Enhanced sonocatalytic degradation of Acid Red 27 with Fe2O3 catalyst: a kinetic study

IF 1.6 4区 工程技术 Q3 Chemical Engineering International Journal of Chemical Reactor Engineering Pub Date : 2024-04-16 DOI:10.1515/ijcre-2024-0040
Suha Abad, Ruqaiya Aziz, Mohd. Junaid Khalil, Muhammad Muhitur Rahman, Mohammad M. Hossain
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Abstract

This study is focused on elucidating the potential effectiveness of degradation as a method to eliminate dyes from aqueous systems. Specifically, it delves into the influence of ultrasound energy on the degradation kinetics of a dye. The research findings underscore the notable impact of ultrasound energy in accelerating the reaction rate constant (k p), with the degradation kinetics exhibiting a conformity to first-order kinetics. An integral aspect of the study involves the establishment of a robust relationship between time and concentration by integrating the equation governing the degradation of the dye. Additionally, the determination of the rate constant, derived from the gradients of the graphs, attests to the model’s fitting accuracy. Intriguingly, the outcomes of this analysis reveal no discernible structural changes in the dye. The accuracy of the model is further underscored by the establishment of linear relations derived from experimental data. Summarily, this kinetic study provides invaluable insights into the multifaceted impact of ultrasound energy and the Fe2O3 catalytic influence on both the degradation kinetics of the dye. The comprehensive nature of the investigation enhances our understanding of the intricate processes involved, contributing significantly to the broader field of water treatment and dye removal from aqueous environments.
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利用 Fe2O3 催化剂增强酸性红 27 的声催化降解:动力学研究
本研究的重点是阐明降解作为一种消除水性体系中染料的方法的潜在有效性。具体来说,它研究了超声波能量对染料降解动力学的影响。研究结果强调了超声波能量在加速反应速率常数(k p)方面的显著影响,降解动力学符合一阶动力学。这项研究的一个重要方面是,通过对控制染料降解的方程进行积分,在时间和浓度之间建立了稳健的关系。此外,根据图形梯度确定的速率常数也证明了模型拟合的准确性。耐人寻味的是,分析结果显示染料没有发生明显的结构变化。根据实验数据建立的线性关系进一步证明了模型的准确性。总之,这项动力学研究为了解超声波能量和 Fe2O3 催化作用对染料降解动力学的多方面影响提供了宝贵的见解。这项研究的全面性增强了我们对所涉及的复杂过程的理解,为更广泛的水处理领域和水环境中的染料去除做出了重要贡献。
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来源期刊
CiteScore
2.80
自引率
12.50%
发文量
107
审稿时长
3 months
期刊介绍: The International Journal of Chemical Reactor Engineering covers the broad fields of theoretical and applied reactor engineering. The IJCRE covers topics drawn from the substantial areas of overlap between catalysis, reaction and reactor engineering. The journal is presently edited by Hugo de Lasa and Charles Xu, counting with an impressive list of Editorial Board leading specialists in chemical reactor engineering. Authors include notable international professors and R&D industry leaders.
期刊最新文献
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