Thermodynamic constraints on kinetic perturbations of homogeneous driven diffusions

Qi Gao, Hyun-Myung Chun, Jordan M. Horowitz
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Abstract

We analyze the static response to kinetic perturbations of nonequilibrium steady states that can be modeled as diffusions. We demonstrate that kinetic response is purely a nonequilibirum effect, measuring the degree to which the Fluctuation-Dissipation Theorem is violated out of equilibrium. For driven diffusions in a flat landscape, we further demonstrate that such response is constrained by the strength of the nonequilibrium driving via quantitative inequalities.
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均质驱动扩散动力学扰动的热力学约束
我们分析了非平衡稳态对动力学扰动的静态响应,这种扰动可被模拟为扩散。我们通过测量非平衡状态下违反波动-消散定理的程度,证明动力学响应纯粹是一种非平衡效应。对于平坦景观中的驱动扩散,我们进一步证明,这种响应通过定量不等式受到非平衡驱动强度的限制。
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