Densification Behaviours of TiC/Ni Metal Ceramic Alloys Produced by Powder Metallurgy

Lahcene Mebarki, Abdelyamine Boukhobza, Kamel Fedaoui, Baroura Lazhar
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Abstract

Ceramic Metallic Alloys of TiC/Ni, Comprising Titanium Carbide with Nickel Contents of 5%, 15%, 30%, and 50%, were Fabricated through Solid-Phase Sintering at 1400°C with a 2-hour Holding Time and a Pressure of 50MPa. This Study Explores the Impact of Nickel Content on the Mechanical and Structural Properties. The Solidification Mechanism between TiC and Ni is Governed by Carbon Diffusion through TiC Particles, Affecting the Morphology of TiC and Carbon Particles in Ni Samples. The Reaction Behavior within the TiC/Ni Alloys was Analyzed, and Microstructural and Mechanical Characteristics were Examined to Evaluate the Influence of Varying Nickel Contents. Results indicate that in all samples, the TiC matrix exhibited a solid solution of the FCC phase. The reaction mechanism of Ti-C-Ni reveals the evolution of solid phase formation with increasing nickel content. As nickel content increases, the mass and size of nickel particles grow, leading to a more uniform and homogeneous structure. At a nickel content of 15%, the samples displayed a bending strength of 1200 ± 50 N, a microhardness of 800 ± 20 (HV 0.1), and a density of 5.6 ± 0.2.
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粉末冶金法生产的 TiC/Ni 金属陶瓷合金的致密化行为
通过在 1400°C、2 小时保温时间和 50MPa 压力下进行固相烧结,制造出了由镍含量分别为 5%、15%、30% 和 50%的碳化钛组成的 TiC/Ni 陶瓷金属合金。本研究探讨了镍含量对机械和结构性能的影响。TiC 和镍之间的凝固机制受碳通过 TiC 颗粒扩散的制约,从而影响镍样品中 TiC 和碳颗粒的形态。分析了 TiC/Ni 合金内部的反应行为,并研究了微观结构和机械特性,以评估不同镍含量的影响。结果表明,在所有样品中,TiC 基体都呈现出 FCC 相的固溶体。Ti-C-Ni 的反应机理揭示了固相形成随镍含量增加而演变的过程。随着镍含量的增加,镍颗粒的质量和尺寸也随之增加,从而形成了更加均匀和一致的结构。镍含量为 15%时,样品的抗弯强度为 1200 ± 50 N,显微硬度为 800 ± 20(HV 0.1),密度为 5.6 ± 0.2。
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