HEAVY METALS DETECTION IN SOME TYPES OF HERBS USED IN MEDICAL TREATMENTS

W. Al-Dahhan, Muataz Adnan Ali, Amer Adnan Hasan, Hassan Nasir Hashim, Baqir Abdualatif Altimmime, Y. Imran, Ali Hadi Jawad, Emad Abdul-Hussain Yousif
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Abstract

Given the backdrop of the Corona pandemic, the objective of this study was to identify some of the heavy metal presence in specific herbs collected from local markets in Iraq. Eight samples were selected, with four (Chamomile, Laurus nobilis, Artemisia, and Borage) used for COVID-19 prevention and the remaining four (Quince, Clove, Thyme, and Propolis) for treating COVID-19 patients. For the detection of metals in the selected specimens, EDX (energy-dispersive X-ray spectroscopy) was employed. The results revealed the existence of  (Ca), (K), (S), (Si), (Al), (Mg), and (Zn) in Chamomile; (K), (Si), (Al), and (Zn) in Laurus nobilis; (Ca), (K), (S), (Si), (Al), (Mg), and (Zn) in Artemisia; (Ca), (K), (P), (Si), (Al), (Mg), and (Zn) in Borage; (Ca), (K), (S), (Si), (Mg), and zinc (Zn) in Quince; (Ca), (K), (Mg), and zinc (Zn) in Clove; (Ca), (K), (Si), (Al), and (Zn) in Thyme; and (Si) in Propolis. All the detected elements are considered essential metals, which are crucial for living biological systems and needed in relatively low concentrations. It is worth mentioning that the selected samples did not contain toxic heavy metals such as (Cd), (Pb), and (Hg), which are regarded as biochemically nonessential. Further analysis for heavy metal content, starting from acid digestion. This process aimed to liberate heavy metals from organic components in the herb samples. The results obtained through atomic absorption confirmed the absence of toxic heavy elements (Cd, Pb, and Hg). This is considered a positive thing as far as these toxic elements are concerned.
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在某些用于医疗的草药中检测到重金属
鉴于科罗娜大流行的背景,本研究的目的是确定从伊拉克当地市场收集的特定草药中存在的一些重金属。研究选取了八个样本,其中四个(洋甘菊、月桂、青蒿和琉璃苣)用于预防 COVID-19,其余四个(榅桲、丁香、百里香和蜂胶)用于治疗 COVID-19 患者。为了检测所选标本中的金属,采用了 EDX(能量色散 X 射线光谱法)。结果显示,洋甘菊中含有(钙)、(钾)、(硒)、(硅)、(铝)、(镁)和(锌);月桂中含有(钾)、(硒)、(铝)和(锌);青蒿中含有(钙)、(钾)、(硒)、(硅)、(铝)、(镁)和(锌);(琉璃苣中的(钙)、(钾)、(磷)、(硅)、(铝)、(镁)和(锌);榅桲中的(钙)、(钾)、(硅)、(镁)和(锌);丁香中的(钙)、(钾)、(镁)和(锌);百里香中的(钙)、(钾)、(硅)、(铝)和(锌);以及蜂胶中的(硅)。所有检测到的元素都被认为是基本金属,它们对生物系统至关重要,所需的浓度相对较低。值得一提的是,所选样本不含有毒重金属,如(镉)、(铅)和(汞),这些元素被认为是生物化学上的非必需元素。重金属含量的进一步分析从酸性消化开始。这一过程旨在将重金属从草药样本中的有机成分中分离出来。通过原子吸收获得的结果证实,样品中不含有毒重金属(镉、铅和汞)。就这些有毒元素而言,这是件好事。
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