Effects of antifoaming agents on manufacturing silver dendrites through fluoride-assisted galvanic replacement reaction

Pee-Yew Lee, Chen-Yu Li, Yi-Hong Bai, Hung Ji Huang, Chun-Jen Weng, Yung-Sheng Lin
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Abstract

Abstract In fluoride-assisted galvanic replacement reaction (FAGRR), metallic dendrites are formed simultaneously with hydrogen gas. However, the presence of hydrogen bubbles impedes the reduction of metallic ions to form metallic dendrites. This study investigates the FAGRR approach to manufacturing Ag dendrites where ethanol is incorporated into a AgNO3 reaction solution. The findings of this study demonstrate the efficacy of ethanol as an antifoaming agent in enhancing the deposition of the Ag dendrites during the FAGRR process. The antifoaming effect of ethanol becomes more intense at higher concentrations of AgNO3. The introduction of ethanol into FAGRR can significantly improve the processing efficiency and yield in the limited time for the manufacturing science and engineering.
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消泡剂对通过氟辅助电化学置换反应制造银树枝状物的影响
摘要 在氟辅助电化学置换反应(FAGRR)中,金属枝晶与氢气同时形成。然而,氢气泡的存在阻碍了金属离子还原形成金属枝晶。本研究探讨了 FAGRR 方法,即在 AgNO3 反应溶液中加入乙醇来制造金属枝晶。研究结果表明,在 FAGRR 工艺中,乙醇作为消泡剂可有效提高银树枝状晶的沉积效果。乙醇的消泡效果在 AgNO3 浓度越高时越明显。在 FAGRR 中引入乙醇可在有限的时间内显著提高加工效率和产量,从而促进制造科学和工程学的发展。
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