T. G. Chulkova, D. V. Krutin, I. V. Simdianov, N. N. Saprykina, A. V. Yakimansky
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引用次数: 0
Abstract
The catalytic activity of C,N-chelate diaminocarbene palladium(II) complexes containing the 3,4-diaryl-1Н-pyrrol-2,5-diimine fragment in the Suzuki reaction was studied. Comparative analysis of the catalytic activity of two types of C,N-chelate diaminocarbene complexes containing in the inner sphere, along with the diaminocarbene ligand, two different ligand combinations, (1) organic isocyanide and chloride ligand and (2) two chloride ligands, was performed. The influence of the electronic effects of substituents in the catalyst on the reaction yield was examined.
期刊介绍:
Russian Journal of Applied Chemistry (Zhurnal prikladnoi khimii) was founded in 1928. It covers all application problems of modern chemistry, including the structure of inorganic and organic compounds, kinetics and mechanisms of chemical reactions, problems of chemical processes and apparatus, borderline problems of chemistry, and applied research.