{"title":"Synthesis and Metathesis Polymerization of Nadimide Derived from β-(–)-Pinene","authors":"P. P. Lezhnin, I. V. Nazarov, M. V. Bermeshev","doi":"10.1134/S1070427223080037","DOIUrl":null,"url":null,"abstract":"<p>An optically active norbornene-type monomer was prepared from β-pinene (a monoterpene compound) and <i>cis</i>-5-norbornene-<i>exo</i>-2,3-dicarboxylic anhydride. The metathesis polymerization of this monomer in the presence of the first-generation Grubbs catalyst was studied, and a soluble high-molecular-mass metathesis polymer exhibiting film-forming properties was synthesized in 90% yield. The monomer and polymer structures were confirmed by <sup>1</sup>Н and <sup>13</sup>С NMR spectroscopy. The metathesis polymers obtained were characterized by thermal gravimetric analysis, differential scanning calorimetry, X-ray diffraction analysis, and polarimetry.</p>","PeriodicalId":757,"journal":{"name":"Russian Journal of Applied Chemistry","volume":"96 8","pages":"794 - 800"},"PeriodicalIF":0.6000,"publicationDate":"2024-04-23","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Russian Journal of Applied Chemistry","FirstCategoryId":"92","ListUrlMain":"https://link.springer.com/article/10.1134/S1070427223080037","RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q4","JCRName":"CHEMISTRY, APPLIED","Score":null,"Total":0}
引用次数: 0
Abstract
An optically active norbornene-type monomer was prepared from β-pinene (a monoterpene compound) and cis-5-norbornene-exo-2,3-dicarboxylic anhydride. The metathesis polymerization of this monomer in the presence of the first-generation Grubbs catalyst was studied, and a soluble high-molecular-mass metathesis polymer exhibiting film-forming properties was synthesized in 90% yield. The monomer and polymer structures were confirmed by 1Н and 13С NMR spectroscopy. The metathesis polymers obtained were characterized by thermal gravimetric analysis, differential scanning calorimetry, X-ray diffraction analysis, and polarimetry.
期刊介绍：
Russian Journal of Applied Chemistry (Zhurnal prikladnoi khimii) was founded in 1928. It covers all application problems of modern chemistry, including the structure of inorganic and organic compounds, kinetics and mechanisms of chemical reactions, problems of chemical processes and apparatus, borderline problems of chemistry, and applied research.
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