Nanostructures embedded on porous materials for the catalytic reduction of nitrophenols: a concise review

IF 2.5 4区 材料科学 Q2 CHEMISTRY, APPLIED Journal of Porous Materials Pub Date : 2024-04-26 DOI:10.1007/s10934-024-01618-4
Alvin Lim Teik Zheng, Ellie Yi Lih Teo, Sivasangar Seenivasagam, Yiu Pang Hung, Supakorn Boonyuen, Eric Lim Teik Chung, Jacqueline Lease, Yoshito Andou
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Abstract

The reduction of nitrophenols is a broadly accepted model for catalytic processes. Incorporating nanostructures into porous materials is becoming more widely acknowledged for its great importance. This strategy has attracted much interest because of its exceptional features imparted on the catalysts, offering enormous promise in accelerating the reduction of nitrophenols. In recent years, various nanostructures have been embedded to a wide range of porous materials, such as carbon, silica, metal-organic frameworks, and other inorganic materials. These porous frameworks possess unique physical and chemical characteristics, making them well-suited for catalytic applications. This thorough review begins by explaining the mechanism of nitrophenol reduction, exploring several nanostructures based on noble metals that are commonly used for catalytic reduction. Following that, a systematic description and comparison of nitrophenols catalytic reduction using various nanostructures on porous templates such as carbon-based, silica-based, zeolite-based, polymer-based, and metal-organic frameworks (MOF) were explained. In addition, this paper also examines several functional materials to enhance the catalytic reduction of nitrophenols. Herein, this write-up intends to narrow the knowledge gap on the recently synthesized catalysts and the practical requirements for removing nitrophenol. This write-up is hoped to offer valuable insights that can aid in the practical utilization of these catalysts for wastewater remediation applications.

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嵌入多孔材料的纳米结构用于硝基苯酚的催化还原:简明综述
硝基苯酚还原是一种广为接受的催化过程模型。在多孔材料中加入纳米结构的重要性日益得到广泛认可。这种策略因其赋予催化剂的特殊功能而备受关注,在加速硝基苯酚还原方面前景广阔。近年来,各种纳米结构已被嵌入到各种多孔材料中,如碳、二氧化硅、金属有机框架和其他无机材料。这些多孔框架具有独特的物理和化学特性,非常适合催化应用。本综述首先解释了硝基苯酚还原的机理,探讨了几种常用于催化还原的基于贵金属的纳米结构。随后,系统地描述和比较了在多孔模板(如碳基、硅基、沸石基、聚合物基和金属有机框架 (MOF))上使用各种纳米结构催化还原硝基苯酚的情况。此外,本文还研究了几种增强硝基苯酚催化还原的功能材料。本文旨在缩小最近合成的催化剂和去除硝基苯酚的实际要求方面的知识差距。希望这篇文章能提供有价值的见解,帮助实际利用这些催化剂进行废水修复应用。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
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来源期刊
Journal of Porous Materials
Journal of Porous Materials 工程技术-材料科学:综合
CiteScore
4.80
自引率
7.70%
发文量
203
审稿时长
2.6 months
期刊介绍: The Journal of Porous Materials is an interdisciplinary and international periodical devoted to all types of porous materials. Its aim is the rapid publication of high quality, peer-reviewed papers focused on the synthesis, processing, characterization and property evaluation of all porous materials. The objective is to establish a unique journal that will serve as a principal means of communication for the growing interdisciplinary field of porous materials. Porous materials include microporous materials with 50 nm pores. Examples of microporous materials are natural and synthetic molecular sieves, cationic and anionic clays, pillared clays, tobermorites, pillared Zr and Ti phosphates, spherosilicates, carbons, porous polymers, xerogels, etc. Mesoporous materials include synthetic molecular sieves, xerogels, aerogels, glasses, glass ceramics, porous polymers, etc.; while macroporous materials include ceramics, glass ceramics, porous polymers, aerogels, cement, etc. The porous materials can be crystalline, semicrystalline or noncrystalline, or combinations thereof. They can also be either organic, inorganic, or their composites. The overall objective of the journal is the establishment of one main forum covering the basic and applied aspects of all porous materials.
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