Partitioning of the High Level Radioactive Waste from the Purex Process by 40% TBF in Isoparaffin Using Magnesium Nitrate as a Salting-out Agent

IF 0.9 Q4 CHEMISTRY, INORGANIC & NUCLEAR Radiochemistry Pub Date : 2024-04-23 DOI:10.1134/s1066362224010065
M. V. Mamchich, A. A. Naumov, N. D. Goletskii, E. A. Puzikov, A. N. Viznyi>, A. V. Bizin, A. I. Medvedeva
{"title":"Partitioning of the High Level Radioactive Waste from the Purex Process by 40% TBF in Isoparaffin Using Magnesium Nitrate as a Salting-out Agent","authors":"M. V. Mamchich, A. A. Naumov, N. D. Goletskii, E. A. Puzikov, A. N. Viznyi>, A. V. Bizin, A. I. Medvedeva","doi":"10.1134/s1066362224010065","DOIUrl":null,"url":null,"abstract":"<h3 data-test=\"abstract-sub-heading\">Abstract</h3><p>Centrifugal contactor rig trials of the partitioning flowsheet were carried out using simulated and real high level waste solutions obtained by reprocessing of WWER-100 spent nuclear fuel with burn-up of 47 MW day/t. 40% TBP in Isopar M was used as a solvent with magnesium nitrate as a salting-out agent. Complete removal of Cs, Sr, Zr, and Mo to raffinate was achieved. Rare earth elements, Am and Cm were totally concentrated in TPE and REE product. Comparison of the results of this work and previous trials with iron(III) nitrate as a salting-out agent [1] demonstrated that the use of magnesium nitrate instead of iron(III) nitrate resulted in higher decontamination factors of TPE and REE fraction from Cs (about 10 000) while in the case of iron(III) nitrate they are &gt;7500.</p>","PeriodicalId":747,"journal":{"name":"Radiochemistry","volume":null,"pages":null},"PeriodicalIF":0.9000,"publicationDate":"2024-04-23","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Radiochemistry","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.1134/s1066362224010065","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q4","JCRName":"CHEMISTRY, INORGANIC & NUCLEAR","Score":null,"Total":0}
引用次数: 0

Abstract

Centrifugal contactor rig trials of the partitioning flowsheet were carried out using simulated and real high level waste solutions obtained by reprocessing of WWER-100 spent nuclear fuel with burn-up of 47 MW day/t. 40% TBP in Isopar M was used as a solvent with magnesium nitrate as a salting-out agent. Complete removal of Cs, Sr, Zr, and Mo to raffinate was achieved. Rare earth elements, Am and Cm were totally concentrated in TPE and REE product. Comparison of the results of this work and previous trials with iron(III) nitrate as a salting-out agent [1] demonstrated that the use of magnesium nitrate instead of iron(III) nitrate resulted in higher decontamination factors of TPE and REE fraction from Cs (about 10 000) while in the case of iron(III) nitrate they are >7500.

Abstract Image

查看原文
分享 分享
微信好友 朋友圈 QQ好友 复制链接
本刊更多论文
使用硝酸镁作为脱盐剂,在异链烷烃中以 40% TBF 分离来自 Purex 工艺的高放射性废物
摘要 利用对 WWER-100 型乏核燃料(烧失量为 47 兆瓦/天/吨)进行后处理所获得的模拟和实际高浓度废液,对分馏流程图进行了离心接触器钻机试验。使用 Isopar M 中的 40% TBP 作为溶剂,硝酸镁作为除盐剂。铯、锶、锆和钼被完全去除。稀土元素 Am 和 Cm 完全浓缩在 TPE 和 REE 产品中。将这项工作的结果与之前使用硝酸铁(III)作为除盐剂的试验结果[1]进行比较后发现,使用硝酸镁而不是硝酸铁(III)可提高 TPE 和稀土元素馏分的除铯系数(约 10 000),而使用硝酸铁(III)的除铯系数为 7500。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
求助全文
约1分钟内获得全文 去求助
来源期刊
Radiochemistry
Radiochemistry CHEMISTRY, INORGANIC & NUCLEAR-
CiteScore
1.30
自引率
33.30%
发文量
51
期刊介绍: Radiochemistry  is a journal that covers the theoretical and applied aspects of radiochemistry, including basic nuclear physical properties of radionuclides; chemistry of radioactive elements and their compounds; the occurrence and behavior of natural and artificial radionuclides in the environment; nuclear fuel cycle; radiochemical analysis methods and devices; production and isolation of radionuclides, synthesis of labeled compounds, new applications of radioactive tracers; radiochemical aspects of nuclear medicine; radiation chemistry and after-effects of nuclear transformations.
期刊最新文献
Neptunium(VI) Nitrate Complexes with Urea and Terpyridine Derivatives Thermal Stability of Irradiated VP-1AP Anion Exchange Resin Development of a Neutron Activation Analysis Method for Studying the Elemental Composition of Atherosclerotic Plaques Hydrogen Peroxide in the Chemistry of f-Elements Disproportionation of Plutonium(V) in EDTA Solutions
×
引用
GB/T 7714-2015
复制
MLA
复制
APA
复制
导出至
BibTeX EndNote RefMan NoteFirst NoteExpress
×
×
提示
您的信息不完整,为了账户安全,请先补充。
现在去补充
×
提示
您因"违规操作"
具体请查看互助需知
我知道了
×
提示
现在去查看 取消
×
提示
确定
0
微信
客服QQ
Book学术公众号 扫码关注我们
反馈
×
意见反馈
请填写您的意见或建议
请填写您的手机或邮箱
已复制链接
已复制链接
快去分享给好友吧!
我知道了
×
扫码分享
扫码分享
Book学术官方微信
Book学术文献互助
Book学术文献互助群
群 号:481959085
Book学术
文献互助 智能选刊 最新文献 互助须知 联系我们:info@booksci.cn
Book学术提供免费学术资源搜索服务,方便国内外学者检索中英文文献。致力于提供最便捷和优质的服务体验。
Copyright © 2023 Book学术 All rights reserved.
ghs 京公网安备 11010802042870号 京ICP备2023020795号-1