Influence of Gamma Radiation on the Composition and Physicochemical Characteristics of Olefins: Post-Radiation Effects

IF 0.9 Q4 CHEMISTRY, INORGANIC & NUCLEAR Radiochemistry Pub Date : 2024-04-23 DOI:10.1134/S1066362224010120
N. G. Guliyeva, L. Yu. Jabbarova, I. I. Mustafayev, S. F. Aliyeva-Chichek
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Abstract

The effect of gamma radiation on olefins was studied under static conditions at an absorbed dose of 65 kGy and at a dose rate of P = 0.076 Gy/s. The effect of radiation on the physicochemical characteristics and structural and group composition of the resulting olefins has been established. Post-radiation effects were studied immediately after irradiation and during 1, 2, 4, and 7 months later. When fuels are irradiated, polymerization of unsaturated hydrocarbons occurs. After the irradiation cessation, there occurs postpolymerization process. The chemical instability of olefins in fuels leads to the formation of carbon deposits in the engine system, tanks, and valves. IR spectra, iodine values, density, and kinematic viscosity of irradiated samples were measured.

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伽马辐射对烯烃成分和理化特性的影响:辐射后效应
摘要 在吸收剂量为 65 kGy 和剂量率为 P = 0.076 Gy/s 的静态条件下,研究了伽马辐射对烯烃的影响。研究确定了辐射对所生成烯烃的理化特性、结构和基团组成的影响。在辐照后立即以及 1、2、4 和 7 个月期间,对辐照后的影响进行了研究。辐照燃料时,不饱和碳氢化合物会发生聚合反应。辐照停止后,会出现后聚合过程。燃料中的烯烃化学性质不稳定,会在发动机系统、油箱和阀门中形成积碳。测量了辐照样品的红外光谱、碘值、密度和运动粘度。
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来源期刊
Radiochemistry
Radiochemistry CHEMISTRY, INORGANIC & NUCLEAR-
CiteScore
1.30
自引率
33.30%
发文量
51
期刊介绍: Radiochemistry  is a journal that covers the theoretical and applied aspects of radiochemistry, including basic nuclear physical properties of radionuclides; chemistry of radioactive elements and their compounds; the occurrence and behavior of natural and artificial radionuclides in the environment; nuclear fuel cycle; radiochemical analysis methods and devices; production and isolation of radionuclides, synthesis of labeled compounds, new applications of radioactive tracers; radiochemical aspects of nuclear medicine; radiation chemistry and after-effects of nuclear transformations.
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