K. V. Martynov, V. V. Kulemin, E. P. Krasavina, I. A. Rumer, G. V. Kostikova, S. A. Kulyukhin
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引用次数: 0
Abstract
Phase formation in cast stone matrices (CSMs) fabricated through the interaction of comelted basalt with ZrO2 at 1623 K for 5 h on air was studied. Basalt melted under the above conditions contains two spinels (relict and newly formed), clinopyroxene of the composition Mg0.66Ca0.60Fe0.26Ti0.05Al0.66Si1.80O6, and glass as the major phases. When basalt is comelted with ZrO2, taken in a weight ratio of 1 : 1, CSMs containing zircon (ZrSiO4), glass, and baddeleyite (ZrO2) as the major phases are formed. Zirconium is concentrated mainly in two phases, zircon and baddeleyite. The rate of Zr leaching from the synthesized CSMs into H2O after 28 days is ~1.0 × 10–9 g/(cm2 day).
期刊介绍：
Radiochemistry is a journal that covers the theoretical and applied aspects of radiochemistry, including basic nuclear physical properties of radionuclides; chemistry of radioactive elements and their compounds; the occurrence and behavior of natural and artificial radionuclides in the environment; nuclear fuel cycle; radiochemical analysis methods and devices; production and isolation of radionuclides, synthesis of labeled compounds, new applications of radioactive tracers; radiochemical aspects of nuclear medicine; radiation chemistry and after-effects of nuclear transformations.
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