Geochemistry and sources of boron and strontium of geothermal waters from the Pearl River Delta region, South China: Implications for water-rock interactions
{"title":"Geochemistry and sources of boron and strontium of geothermal waters from the Pearl River Delta region, South China: Implications for water-rock interactions","authors":"Zhengan Wei , Shaopeng Huang , Chengshan Wang","doi":"10.1016/j.gexplo.2024.107492","DOIUrl":null,"url":null,"abstract":"<div><p>Pearl River Delta (PRD) region of South China is abundant of geothermal water resources. However, the development and utilization level of geothermal resources in this region is relatively low, due in part to the lack of fundamental geochemical research. To access water-rock interaction processes of the PRD geothermal system, we analyzed the geochemistry of geothermal waters by combining trace elements (B, Sr, and Br) and isotopes (δ<sup>11</sup>B and <sup>87</sup>Sr/<sup>86</sup>Sr) with conventional tracers (major elements) that had been reported. The Cl/Br ratios (from 31 to 639) confirm the multi-source salinity of marine origin, precipitation, and a minor dissolution of halite. Major ions chemistry highlights the influence of ions exchange, the dissolution of carbonate, silicate, and sulphate minerals as well as the contribution of seawater. The Cl/B ratios (61 to 22,583) suggest interactions with carbonate rock and felsic rock, input of seawater, and groundwater mixing. Boron isotopic compositions (δ<sup>11</sup>B) range between −9.22 and +39.78 ‰. Sr contents and <sup>87</sup>Sr/<sup>86</sup>Sr ratios are more homogeneous, falling between 0.06 and 32.26 mg/L and between 0.71239 and 0.72121, respectively. The B and Sr isotopic signatures show that three processes contribute to geochemistry of geothermal waters: 1) water/rock interaction involving marine carbonate rock, evaporite, and granitoid or/and gneiss, 2) seawater intrusion, and 3) shallow groundwater mixing. Major-trace element chemistry and these isotope systematics on their own indicates essential information on the aspects of fluid origin or water-rock interaction processes, and however provide a more comprehensive understanding of the geothermal system in the PRD region, South China.</p></div>","PeriodicalId":16336,"journal":{"name":"Journal of Geochemical Exploration","volume":null,"pages":null},"PeriodicalIF":3.4000,"publicationDate":"2024-05-02","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Journal of Geochemical Exploration","FirstCategoryId":"89","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S0375674224001080","RegionNum":2,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q1","JCRName":"GEOCHEMISTRY & GEOPHYSICS","Score":null,"Total":0}
引用次数: 0
Abstract
Pearl River Delta (PRD) region of South China is abundant of geothermal water resources. However, the development and utilization level of geothermal resources in this region is relatively low, due in part to the lack of fundamental geochemical research. To access water-rock interaction processes of the PRD geothermal system, we analyzed the geochemistry of geothermal waters by combining trace elements (B, Sr, and Br) and isotopes (δ11B and 87Sr/86Sr) with conventional tracers (major elements) that had been reported. The Cl/Br ratios (from 31 to 639) confirm the multi-source salinity of marine origin, precipitation, and a minor dissolution of halite. Major ions chemistry highlights the influence of ions exchange, the dissolution of carbonate, silicate, and sulphate minerals as well as the contribution of seawater. The Cl/B ratios (61 to 22,583) suggest interactions with carbonate rock and felsic rock, input of seawater, and groundwater mixing. Boron isotopic compositions (δ11B) range between −9.22 and +39.78 ‰. Sr contents and 87Sr/86Sr ratios are more homogeneous, falling between 0.06 and 32.26 mg/L and between 0.71239 and 0.72121, respectively. The B and Sr isotopic signatures show that three processes contribute to geochemistry of geothermal waters: 1) water/rock interaction involving marine carbonate rock, evaporite, and granitoid or/and gneiss, 2) seawater intrusion, and 3) shallow groundwater mixing. Major-trace element chemistry and these isotope systematics on their own indicates essential information on the aspects of fluid origin or water-rock interaction processes, and however provide a more comprehensive understanding of the geothermal system in the PRD region, South China.
期刊介绍:
Journal of Geochemical Exploration is mostly dedicated to publication of original studies in exploration and environmental geochemistry and related topics.
Contributions considered of prevalent interest for the journal include researches based on the application of innovative methods to:
define the genesis and the evolution of mineral deposits including transfer of elements in large-scale mineralized areas.
analyze complex systems at the boundaries between bio-geochemistry, metal transport and mineral accumulation.
evaluate effects of historical mining activities on the surface environment.
trace pollutant sources and define their fate and transport models in the near-surface and surface environments involving solid, fluid and aerial matrices.
assess and quantify natural and technogenic radioactivity in the environment.
determine geochemical anomalies and set baseline reference values using compositional data analysis, multivariate statistics and geo-spatial analysis.
assess the impacts of anthropogenic contamination on ecosystems and human health at local and regional scale to prioritize and classify risks through deterministic and stochastic approaches.
Papers dedicated to the presentation of newly developed methods in analytical geochemistry to be applied in the field or in laboratory are also within the topics of interest for the journal.