The Highly Durable Antibacterial Gel-like Coatings for Textiles

Seyedali Mirmohammadsadeghi, Davis Juhas, Mikhail Parker, Kristina Peranidze, Dwight Austin Van Horn, Aayushi Sharma, Dhruvi Patel, Tatyana A. Sysoeva, Vladislav Klepov, Vladimir Reukov
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Abstract

Hospital-acquired infections are considered a priority for public health systems, which poses a significant burden for society. High-touch surfaces of healthcare centers, including textiles, provide a suitable environment for pathogenic bacteria to grow, necessitating incorporating effective antibacterial agents into textiles. This paper introduces a highly durable antibacterial gel-like solution, Silver Shell finish, which contains chitosan-bound silver chloride microparticles. The study investigates the coating's environmental impact, health risks, and durability during repeated washing. The structure of the Silver Shell finish was studied using Transmission Electron Microscopy (TEM) and Energy-Dispersive X-ray Spectroscopy (EDX). TEM images showed a core-shell structure, with chitosan forming a protective shell around groupings of silver micro-particles. Field Emission Scanning Electron Microscopy (FESEM) demonstrated the uniform deposition of Silver Shell on the surface of fabrics. AATCC Test Method 100 was employed to quantitatively analyze the antibacterial properties of fabrics coated with silver microparticles. Two types of bacteria, Staphylococcus aureus (S. aureus) and Escherichia coli (E. coli) were used in this study. The antibacterial results showed that after 75 wash cycles, a 100% reduction for both S. aureus and E. coli in the coated samples using crosslinking agents was observed. The coated samples without a crosslinking agent exhibited a 99.88% and 99.81% reduction for S. aureus and E. coli after 50 washing cycles. AATCC-147 was performed to investigate the coated samples' leaching properties and the crosslinking agent's effect against S. aureus and E. coli. All coated samples demonstrated remarkable antibacterial efficacy even after 75 wash cycles.
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用于纺织品的高耐久性抗菌凝胶状涂层
医院获得性感染被认为是公共卫生系统的首要问题,给社会造成了沉重负担。医疗保健中心的高接触表面(包括纺织品)为病原菌的生长提供了适宜的环境,因此有必要在纺织品中加入有效的抗菌剂。本文介绍了一种高度耐用的抗菌凝胶状溶液--银壳整理剂,它含有壳聚糖结合氯化银微粒。研究调查了该涂层对环境的影响、健康风险以及反复洗涤时的耐久性。研究人员使用透射电子显微镜(TEM)和能量色散 X 射线光谱仪(EDX)对银壳表面涂层的结构进行了研究。TEM 图像显示了一种核壳结构,壳聚糖在银微颗粒群周围形成了保护壳。场发射扫描电子显微镜(FESEM)显示银壳均匀地沉积在织物表面。AATCC 测试方法 100 被用来定量分析涂有银微颗粒的织物的抗菌性能。本研究使用了金黄色葡萄球菌(S. aureus)和大肠杆菌(E. coli)两种细菌。抗菌结果表明,经过 75 个洗涤周期后,使用交联剂的涂层样品中的金黄色葡萄球菌和大肠杆菌均减少了 100%。未使用交联剂的涂层样品在 50 次洗涤后,金黄色葡萄球菌和大肠杆菌的减少率分别为 99.88% 和 99.81%。对 AATCC-147 进行了测试,以研究涂层样品的浸出特性以及交联剂对金黄色葡萄球菌和大肠杆菌的作用。即使经过 75 次洗涤,所有涂层样品都表现出了显著的抗菌效果。
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