Sorption of Radium-226 on Few-Layer Graphene Synthesized under Conditions of Self-Propagating High-Temperature Synthesis

IF 1.1 4区 化学 Q4 CHEMISTRY, PHYSICAL Colloid Journal Pub Date : 2024-05-07 DOI:10.1134/S1061933X23601348
A. A. Vozniakovskii, A. P. Voznyakovskii, S. V. Kidalov, A. P. Karmanov, N. G. Rachkova, N. D. Podlozhnyuk
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Abstract

Human industrial activity is accompanied by the formation of vast volumes of water contaminated with radionuclides, including radium-226, which create serious danger to people. Graphene nanostructures are among the most promising materials for purifying water from radionuclides. This work has been devoted to investigating the efficiency of few-layer graphene synthesized under conditions of self-propagating high-temperature synthesis from cellulose and wastes of the woodworking industry (technical lignin, tree bark) for purifying water from radium-226. The key advantage of the method chosen for synthesis of few-layer graphene is the possibility to synthesize large volumes of the material at an acceptable cost, which is extremely important for industrial applications. It has been found that the synthesized samples of few-layer graphene can efficiently purify water from radium-226 (the degree of sorption is higher than 99%). It has also been shown that the degree of desorption upon repeated washing with water does not exceed 0.5%.

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自蔓延高温合成条件下合成的少层石墨烯对镭-226 的吸附作用
摘要 伴随着人类的工业活动,形成了大量受放射性核素(包括镭-226)污染的水,对人类造成严重危害。石墨烯纳米结构是最有希望净化水中放射性核素的材料之一。这项工作致力于研究在纤维素和木材加工业废料(工业木质素、树皮)自发热高温合成条件下合成的几层石墨烯在净化水中镭-226 的效率。选择这种方法合成少层石墨烯的主要优点是可以以可接受的成本合成大量材料,这对工业应用极为重要。研究发现,合成的几层石墨烯样品可以有效地净化水中的镭-226(吸附率高于 99%)。研究还表明,经水反复洗涤后,解吸程度不超过 0.5%。
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来源期刊
Colloid Journal
Colloid Journal 化学-物理化学
CiteScore
2.20
自引率
18.20%
发文量
36
审稿时长
6-12 weeks
期刊介绍: Colloid Journal (Kolloidnyi Zhurnal) is the only journal in Russia that publishes the results of research in the area of chemical science dealing with the disperse state of matter and surface phenomena in disperse systems. The journal covers experimental and theoretical works on a great variety of colloid and surface phenomena: the structure and properties of interfaces; adsorption phenomena and structure of adsorption layers of surfactants; capillary phenomena; wetting films; wetting and spreading; and detergency. The formation of colloid systems, their molecular-kinetic and optical properties, surface forces, interaction of colloidal particles, stabilization, and criteria of stability loss of different disperse systems (lyosols and aerosols, suspensions, emulsions, foams, and micellar systems) are also topics of the journal. Colloid Journal also includes the phenomena of electro- and diffusiophoresis, electro- and thermoosmosis, and capillary and reverse osmosis, i.e., phenomena dealing with the existence of diffusion layers of molecules and ions in the vicinity of the interface.
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