Development of microfiltration membranes based on polysulfone and polyetherimide blends.

IF 2.6 4区 环境科学与生态学 Q3 ENGINEERING, ENVIRONMENTAL Water Science and Technology Pub Date : 2024-05-01 Epub Date: 2024-04-26 DOI:10.2166/wst.2024.135
Sevgi Gunes-Durak
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Abstract

In this study, membranes blended with polysulfone (PSU) and polyetherimide (PEI) polymers in different ratios were fabricated. Their potential to remove pollutants from rivers, which are a potential drinking water source, was investigated. Scanning electron microscopy analysis revealed that the PSU membranes had a dense and homogeneous layer, whereas the addition of PEI formed a spongy substrate. The water content of the fabricated membranes varied between 5.37 and 22.42%, porosities 28.73-89.36%, contact angles 69.18-85.81%, and average pure water fluxes 257.25-375.32 L/m2 h. The blended membranes removed turbidity, chloride, alkalinity, conductivity, sulfate, iron, manganese, and total organic carbon up to 98.32, 92.28, 96.87, 90.67, 99.58, 94.63, 97.48, and 79.11%, respectively. These results show that when PEI was added to the PSU polymer, the filtration efficiency increased owing to an increase in the hydrophilicity of the membranes. Blending these two polymers enabled the optimization of membrane properties such as permeability, selectivity, and mechanical strength. In addition, membrane fabrication processes are simple and incur low costs.

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开发基于聚砜和聚醚酰亚胺混合物的微滤膜。
在这项研究中,以不同比例混合了聚砜(PSU)和聚醚酰亚胺(PEI)聚合物的膜被制成。研究了这些膜去除潜在饮用水源河流中污染物的潜力。扫描电子显微镜分析表明,PSU 膜具有致密均匀的层,而添加 PEI 后则形成了海绵状基底。制成的膜的含水量在 5.37% 和 22.42% 之间,孔隙率为 28.73%-89.36%,接触角为 69.18%-85.81%,平均纯水通量为 257.25-375.32 升/平方米小时。混合膜对浊度、氯化物、碱度、电导率、硫酸盐、铁、锰和总有机碳的去除率分别达到 98.32%、92.28%、96.87%、90.67%、99.58%、94.63%、97.48% 和 79.11%。这些结果表明,在 PSU 聚合物中添加 PEI 后,由于膜的亲水性增加,过滤效率也随之提高。混合这两种聚合物可以优化膜的特性,如渗透性、选择性和机械强度。此外,膜制造工艺简单,成本低。
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来源期刊
Water Science and Technology
Water Science and Technology 环境科学-工程:环境
CiteScore
4.90
自引率
3.70%
发文量
366
审稿时长
4.4 months
期刊介绍: Water Science and Technology publishes peer-reviewed papers on all aspects of the science and technology of water and wastewater. Papers are selected by a rigorous peer review procedure with the aim of rapid and wide dissemination of research results, development and application of new techniques, and related managerial and policy issues. Scientists, engineers, consultants, managers and policy-makers will find this journal essential as a permanent record of progress of research activities and their practical applications.
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