Sanja Djokić , Goran Benedeković , Jelena Kesić , Marko V. Rodić , Mirjana Popsavin , Velimir Popsavin , Jovana Francuz
{"title":"First total synthesis of asperilactone B. Revision of absolute stereochemistry of asperilactones B and C†","authors":"Sanja Djokić , Goran Benedeković , Jelena Kesić , Marko V. Rodić , Mirjana Popsavin , Velimir Popsavin , Jovana Francuz","doi":"10.1039/d4ob00583j","DOIUrl":null,"url":null,"abstract":"<div><p>The first total synthesis and absolute configuration assignment of asperilactone B (<strong>I</strong>) have been accomplished. Additionally, a revision of the absolute stereochemistry of asperilactone C has been done. The first total synthesis of the opposite enantiomer of asperilactone B (<em>ent</em>-<strong>I</strong>) has also been achieved, as well as that of C-7 epimers of both asperilactones B (<strong>8</strong>) and C (<strong>9</strong>).</p></div>","PeriodicalId":96,"journal":{"name":"Organic & Biomolecular Chemistry","volume":"22 24","pages":"Pages 4864-4867"},"PeriodicalIF":2.7000,"publicationDate":"2024-06-19","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Organic & Biomolecular Chemistry","FirstCategoryId":"92","ListUrlMain":"https://www.sciencedirect.com/org/science/article/pii/S1477052024004932","RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q1","JCRName":"CHEMISTRY, ORGANIC","Score":null,"Total":0}
引用次数: 0
Abstract
The first total synthesis and absolute configuration assignment of asperilactone B (I) have been accomplished. Additionally, a revision of the absolute stereochemistry of asperilactone C has been done. The first total synthesis of the opposite enantiomer of asperilactone B (ent-I) has also been achieved, as well as that of C-7 epimers of both asperilactones B (8) and C (9).
期刊介绍：
Organic & Biomolecular Chemistry is an international journal using integrated research in chemistry-organic chemistry. Founded in 2003 by the Royal Society of Chemistry, the journal is published in Semimonthly issues and has been indexed by SCIE, a leading international database. The journal focuses on the key research and cutting-edge progress in the field of chemistry-organic chemistry, publishes and reports the research results in this field in a timely manner, and is committed to becoming a window and platform for rapid academic exchanges among peers in this field. The journal's impact factor in 2023 is 2.9, and its CiteScore is 5.5.
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