Adsorptive and oxidative denitrogenation of fuels using metal–organic frameworks: A review

IF 3 4区 工程技术 Q3 CHEMISTRY, PHYSICAL Adsorption Pub Date : 2024-05-08 DOI:10.1007/s10450-024-00453-y
Amin Alamdari, Fatemeh Hajipour Alamdari
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Abstract

Increasing demand for fossil fuels in worldwide leads to environmental issues. Fossil fuel containing nitrogen compounds is deactivating the industrial catalysts. There are several techniques for nitrogen removal such as hydrodenitrogenation, oxidative denitrogenation, and adsorptive denitrogenation, due to the restriction of the common method; Researchers have suggested metal–organic frameworks (MOFs) and MOF nanocomposite materials for adsorptive denitrogenation (ADN) and oxidative denitrogenation (ODN) of fuels in recent years. This review paper aims to investigate the adsorptive and oxidative denitrogenation of liquid fuels with MOFs-based catalysts. All catalysts including pristine MOFs, defected MOFs, active component-loaded MOFs, and MOF-derived carbonaceous materials are studied. The detailed mechanisms of different MOFs are investigated to further improvements and modifications to synthesis well catalysts for nitrogen compound removal from liquid fuels.

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利用金属有机框架对燃料进行吸附和氧化脱氮:综述
全球对化石燃料的需求日益增长,导致了环境问题。化石燃料中含有的氮化合物会使工业催化剂失活。由于普通方法的局限性,脱氮技术有多种,如加氢脱氮、氧化脱氮和吸附脱氮;近年来,研究人员提出了金属有机框架(MOFs)和 MOF 纳米复合材料用于燃料的吸附脱氮(ADN)和氧化脱氮(ODN)。本综述论文旨在研究使用基于 MOFs 的催化剂对液体燃料进行吸附脱氮和氧化脱氮的问题。本文研究了所有催化剂,包括原始 MOFs、缺陷 MOFs、活性组分负载 MOFs 和 MOF 衍生碳质材料。研究了不同 MOFs 的详细机理,以便进一步改进和改良用于脱除液体燃料中氮化合物的合成催化剂。
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来源期刊
Adsorption
Adsorption 工程技术-工程:化工
CiteScore
8.10
自引率
3.00%
发文量
18
审稿时长
2.4 months
期刊介绍: The journal Adsorption provides authoritative information on adsorption and allied fields to scientists, engineers, and technologists throughout the world. The information takes the form of peer-reviewed articles, R&D notes, topical review papers, tutorial papers, book reviews, meeting announcements, and news. Coverage includes fundamental and practical aspects of adsorption: mathematics, thermodynamics, chemistry, and physics, as well as processes, applications, models engineering, and equipment design. Among the topics are Adsorbents: new materials, new synthesis techniques, characterization of structure and properties, and applications; Equilibria: novel theories or semi-empirical models, experimental data, and new measurement methods; Kinetics: new models, experimental data, and measurement methods. Processes: chemical, biochemical, environmental, and other applications, purification or bulk separation, fixed bed or moving bed systems, simulations, experiments, and design procedures.
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