Preparation of Superhydrophilic UiO-66-NH2@PMAA Metal-Organic Framework Materials by Hydrothermal Reaction Coupled with Gamma Ray Irradiation Method

IF 0.9 4区 化学 Q4 CHEMISTRY, PHYSICAL High Energy Chemistry Pub Date : 2024-05-13 DOI:10.1134/s0018143924700061
Kai Fan, Junwei Zhou, Chuanyang Gao, Jinshen Lei, Jinjie Qin, Xiaoying Liu
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Abstract

In this study, the UiO-66-NH2@PMAA metal-organic framework was prepared by using a hydrothermal reaction coupled with the gamma-ray irradiation method. The chemical structure of the product was studied using FTIR and XPS before and after irradiation, indicating the efficient development of the grafting reaction. The DSC results revealed a drop in the melting point of UiO-66-NH2@PMAA material, which might be attributed to PMAM grafting. Following that, different MOF materials were suction-filtered onto the surface of the membrane, and the alteration of their contact angle with time was recorded, indicating the enhancement of UiO-66-NH2@PMAA materials’ hydrophilicity. The modified MOF material has better dispersibility in aqueous solutions, providing reference significance for its application in related fields.

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水热反应与伽马射线辐照法制备超亲水性 UiO-66-NH2@PMAA 金属有机框架材料
摘要 本研究采用水热反应结合伽马射线辐照法制备了UiO-66-NH2@PMAA金属有机框架。利用傅立叶变换红外光谱和 XPS 对辐照前后的产物化学结构进行了研究,结果表明接枝反应进行得很顺利。DSC 结果显示 UiO-66-NH2@PMAA 材料的熔点下降,这可能是 PMAM 接枝的结果。随后,将不同的 MOF 材料吸滤到膜表面,记录其接触角随时间的变化,表明 UiO-66-NH2@PMAA 材料的亲水性增强。改性后的 MOF 材料在水溶液中具有更好的分散性,为其在相关领域的应用提供了参考意义。
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来源期刊
High Energy Chemistry
High Energy Chemistry 化学-物理化学
CiteScore
1.50
自引率
28.60%
发文量
62
审稿时长
6-12 weeks
期刊介绍: High Energy Chemistry publishes original articles, reviews, and short communications on molecular and supramolecular photochemistry, photobiology, radiation chemistry, plasma chemistry, chemistry of nanosized systems, chemistry of new atoms, processes and materials for optical information systems and other areas of high energy chemistry. It publishes theoretical and experimental studies in all areas of high energy chemistry, such as the interaction of high-energy particles with matter, the nature and reactivity of short-lived species induced by the action of particle and electromagnetic radiation or hot atoms on substances in their gaseous and condensed states, and chemical processes initiated in organic and inorganic systems by high-energy radiation.
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