M. B. Pshenitsyn, O. A. Boeva, A. S. Konopatsky, A. Yu. Antonov, K. N. Zhavoronkova
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引用次数: 0
Abstract
The purpose of this work was to study the catalytic properties of mono- and bimetallic nanoparticles of the copper–silver system of variable composition supported on aluminum oxide in the conversion reactions of protium modifications and deuterium–hydrogen exchange. From a comparison of the temperature dependences of the specific catalytic activity of samples in the two test reactions, a conclusion on different reaction mechanisms was drawn. It was shown that, compared to the bulk metals, CunAgm nanoparticles had catalytic properties over a wide temperature range down to –196°C. In the chemical reaction of isotope exchange in molecular hydrogen, a synergistic effect was observed, which indicated the interaction of metals in bimetallic nanoparticles.
期刊介绍：
Kinetics and Catalysis Russian is a periodical that publishes theoretical and experimental works on homogeneous and heterogeneous kinetics and catalysis. Other topics include the mechanism and kinetics of noncatalytic processes in gaseous, liquid, and solid phases, quantum chemical calculations in kinetics and catalysis, methods of studying catalytic processes and catalysts, the chemistry of catalysts and adsorbent surfaces, the structure and physicochemical properties of catalysts, preparation and poisoning of catalysts, macrokinetics, and computer simulations in catalysis. The journal also publishes review articles on contemporary problems in kinetics and catalysis. The journal welcomes manuscripts from all countries in the English or Russian language.
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