IR-Absorption in Ti/(Si)/SiO2/Si3N4/n+-Si Structures with an Island Surface Layer of Various Horizontal Geometries

IF 0.8 4区 化学 Q4 SPECTROSCOPY Journal of Applied Spectroscopy Pub Date : 2024-05-10 DOI:10.1007/s10812-024-01722-y
A. I. Mukhammad, P. I. Gaiduk
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Abstract

Theoretically calculated IR absorption spectra of Ti/SiO2/Si3N4/n+-Si structures with an island surface layer were used to show that the absorption maximum broadened and shifted to longer wavelength as the n+-Si island size increased with a constant period of their placement on the surface. This peak was probably associated with excitation of plasmon oscillations in the surface island layer. A structure with an island size of 3 μm and a period of 6 μm was shown to absorb ~99% of the incident radiation at a wavelength practically equal to the period (6.2 μm). Other absorption bands at ~4 μm and 9.0–9.5 μm arose regardless of the island size and were associated with absorption in the SiO2 layer. A layer of undoped silicon of thickness up to 200 nm located between the Ti substrate and SiO2 layer slightly reduced the intensity and half-width of the plasmon absorption maximum.

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具有不同水平几何形状岛状表面层的 Ti/(Si)/SiO2/Si3N4/n+-Si 结构中的红外吸收
利用理论计算得出的具有岛状表面层的 Ti/SiO2/Si3N4/n+-Si 结构的红外吸收光谱表明,随着 n+-Si 岛尺寸的增大,吸收最大值变宽并移至更长的波长,而其在表面的放置周期保持不变。这个峰值可能与表面岛层的等离子振荡激发有关。结果表明,硅岛尺寸为 3 μm、周期为 6 μm 的结构在波长几乎等于周期(6.2 μm)时吸收了约 99% 的入射辐射。在 ~4 μm 和 9.0-9.5 μm 处出现的其他吸收带与岛的大小无关,与二氧化硅层的吸收有关。在钛衬底和二氧化硅层之间有一层厚度达 200 纳米的未掺杂硅层,这层硅层略微降低了等离子体吸收最大值的强度和半宽度。
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来源期刊
CiteScore
1.30
自引率
14.30%
发文量
145
审稿时长
2.5 months
期刊介绍: Journal of Applied Spectroscopy reports on many key applications of spectroscopy in chemistry, physics, metallurgy, and biology. An increasing number of papers focus on the theory of lasers, as well as the tremendous potential for the practical applications of lasers in numerous fields and industries.
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