{"title":"IR-Absorption in Ti/(Si)/SiO2/Si3N4/n+-Si Structures with an Island Surface Layer of Various Horizontal Geometries","authors":"A. I. Mukhammad, P. I. Gaiduk","doi":"10.1007/s10812-024-01722-y","DOIUrl":null,"url":null,"abstract":"<p>Theoretically calculated IR absorption spectra of Ti/SiO<sub>2</sub>/Si<sub>3</sub>N4/<i>n</i><sup>+</sup>-Si structures with an island surface layer were used to show that the absorption maximum broadened and shifted to longer wavelength as the <i>n</i><sup>+</sup>-Si island size increased with a constant period of their placement on the surface. This peak was probably associated with excitation of plasmon oscillations in the surface island layer. A structure with an island size of 3 μm and a period of 6 μm was shown to absorb ~99% of the incident radiation at a wavelength practically equal to the period (6.2 μm). Other absorption bands at ~4 μm and 9.0–9.5 μm arose regardless of the island size and were associated with absorption in the SiO<sub>2</sub> layer. A layer of undoped silicon of thickness up to 200 nm located between the Ti substrate and SiO<sub>2</sub> layer slightly reduced the intensity and half-width of the plasmon absorption maximum<i>.</i></p>","PeriodicalId":609,"journal":{"name":"Journal of Applied Spectroscopy","volume":"91 2","pages":"307 - 312"},"PeriodicalIF":0.8000,"publicationDate":"2024-05-10","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Journal of Applied Spectroscopy","FirstCategoryId":"92","ListUrlMain":"https://link.springer.com/article/10.1007/s10812-024-01722-y","RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q4","JCRName":"SPECTROSCOPY","Score":null,"Total":0}
引用次数: 0
Abstract
Theoretically calculated IR absorption spectra of Ti/SiO2/Si3N4/n+-Si structures with an island surface layer were used to show that the absorption maximum broadened and shifted to longer wavelength as the n+-Si island size increased with a constant period of their placement on the surface. This peak was probably associated with excitation of plasmon oscillations in the surface island layer. A structure with an island size of 3 μm and a period of 6 μm was shown to absorb ~99% of the incident radiation at a wavelength practically equal to the period (6.2 μm). Other absorption bands at ~4 μm and 9.0–9.5 μm arose regardless of the island size and were associated with absorption in the SiO2 layer. A layer of undoped silicon of thickness up to 200 nm located between the Ti substrate and SiO2 layer slightly reduced the intensity and half-width of the plasmon absorption maximum.
期刊介绍:
Journal of Applied Spectroscopy reports on many key applications of spectroscopy in chemistry, physics, metallurgy, and biology. An increasing number of papers focus on the theory of lasers, as well as the tremendous potential for the practical applications of lasers in numerous fields and industries.