A Floral Revolution: Unveiling the Potential and Catalytic Brilliance of Bimetallic Nanoflowers

IF 2.7 4区 化学 Q2 CHEMISTRY, INORGANIC & NUCLEAR Journal of Cluster Science Pub Date : 2024-05-11 DOI:10.1007/s10876-024-02629-6
Shahnawaz Ahmad Bhat, Sujeet K. Mishra, Vijay Kumar, Poonam Dwivedi, Bushra Yaseen, Yashika Gandhi, Hemant Rawat, Ch Venkata Narasimhaji
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Abstract

The novel flower shaped nanomaterials, known as Nanoflowers (NFs), have attracted the interest of the scientific community around the world with their unique morphology, ease of synthesis, large surface-to-volume ratio, and high electron conductivity, making them a promising nanomaterial for various relevant applications. Bimetallic NFs comprise of two different metallic elements, with superior properties due to the synergistic effect between the hereditary properties of the constituent metal atoms. Bimetallic NFs can be synthesized through various methods, each offering unique advantages. Conventional methods provide a traditional approach to NF synthesis, while electrodeposition methods offer precise control over NF morphology and composition. Biological methods harness the power of biological systems for green and sustainable NF synthesis. Various characterization techniques for identifying the morphology of NFs include HR-TEM, SEM, EDX, XRD etc. These NFs exhibit exemplary catalytic activity with high selectivity and catalytic yield due to their large surface areas and augmented active site density. This review delineates the synthesis, morphology, electronic properties and catalytic applications of bimetallic NFs. The manuscript depicts various catalytic reactions and focuses on mechanism and role of bimetallic NFs in these reactions. Moreover, the recent challenges and future prospects of these bimetallic NFs are well discussed in detail.

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一场花卉革命:揭示双金属纳米花的潜力和催化光彩
被称为 "纳米花"(NFs)的新型花形纳米材料以其独特的形态、易合成性、大表面体积比和高电子传导性吸引了全球科学界的兴趣,使其成为一种在各种相关应用中大有可为的纳米材料。双金属 NFs 由两种不同的金属元素组成,由于组成金属原子的遗传特性之间的协同效应而具有优异的性能。双金属无纺布可通过各种方法合成,每种方法都具有独特的优势。传统方法提供了合成 NF 的传统方法,而电沉积方法则能精确控制 NF 的形态和组成。生物方法利用生物系统的力量,实现绿色和可持续的 NF 合成。用于鉴定 NF 形态的各种表征技术包括 HR-TEM、SEM、EDX、XRD 等。这些 NF 因其较大的表面积和更高的活性位点密度而表现出典范的催化活性,具有较高的选择性和催化产率。本综述介绍了双金属 NF 的合成、形态、电子特性和催化应用。手稿描述了各种催化反应,并重点介绍了双金属 NFs 在这些反应中的机理和作用。此外,还详细讨论了这些双金属 NFs 最近面临的挑战和未来前景。
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来源期刊
Journal of Cluster Science
Journal of Cluster Science 化学-无机化学与核化学
CiteScore
6.70
自引率
0.00%
发文量
166
审稿时长
3 months
期刊介绍: The journal publishes the following types of papers: (a) original and important research; (b) authoritative comprehensive reviews or short overviews of topics of current interest; (c) brief but urgent communications on new significant research; and (d) commentaries intended to foster the exchange of innovative or provocative ideas, and to encourage dialogue, amongst researchers working in different cluster disciplines.
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