{"title":"3D Coordination Polymers with N-Heterocyclic Ga(I) Moieties","authors":"T. S. Koptseva, E. V. Baranov, I. L. Fedushkin","doi":"10.1134/S1070328423601127","DOIUrl":null,"url":null,"abstract":"<p>The reactions of bimetallic acenaphthene-1,2-diimine complex [(Dpp-bian-GaCr(CO)<sub>5</sub>]<sub>2</sub>-[Na(Thf)<sub>2</sub>]<sub>2</sub> (<b>I</b>) (Dpp-bian = 1,2-bis[(2,6-diisopropylphenyl)imino]acenaphthene) with 4,4'-bipyridine (4,4'-Bipy) and 1,3-bis(4-pyridyl)propane (Bpp) in THF gave 3D coordination polymers [{(Dpp-bian)GaCr(CO)<sub>5</sub>}{Na(4,4'-Bipy)<sub>3</sub>}]<sub><i>n</i></sub> (<b>II</b>) and [(Dpp-bian)GaCr(CO)<sub>4</sub>Na(Et<sub>2</sub>O)(Bpp)<sub>1,5</sub>]<sub><i>n</i></sub> (<b>III</b>), respectively. Compounds <b>II</b> and <b>III</b> were characterized by elemental analysis and NMR and IR spectroscopy. The molecular structure of <b>II</b> was established by X-ray diffraction (CCDC no. 2278024).</p>","PeriodicalId":759,"journal":{"name":"Russian Journal of Coordination Chemistry","volume":"50 2","pages":"85 - 95"},"PeriodicalIF":1.1000,"publicationDate":"2024-05-08","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Russian Journal of Coordination Chemistry","FirstCategoryId":"92","ListUrlMain":"https://link.springer.com/article/10.1134/S1070328423601127","RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q4","JCRName":"CHEMISTRY, INORGANIC & NUCLEAR","Score":null,"Total":0}
引用次数: 0
Abstract
The reactions of bimetallic acenaphthene-1,2-diimine complex [(Dpp-bian-GaCr(CO)5]2-[Na(Thf)2]2 (I) (Dpp-bian = 1,2-bis[(2,6-diisopropylphenyl)imino]acenaphthene) with 4,4'-bipyridine (4,4'-Bipy) and 1,3-bis(4-pyridyl)propane (Bpp) in THF gave 3D coordination polymers [{(Dpp-bian)GaCr(CO)5}{Na(4,4'-Bipy)3}]n (II) and [(Dpp-bian)GaCr(CO)4Na(Et2O)(Bpp)1,5]n (III), respectively. Compounds II and III were characterized by elemental analysis and NMR and IR spectroscopy. The molecular structure of II was established by X-ray diffraction (CCDC no. 2278024).
摘要双金属苊-1,2-二亚胺配合物[(Dpp-bian-GaCr(CO)5]2-[Na(Thf)2]2 (I)（Dpp-bian = 1,2-双[(2,6-二异丙基苯基)亚氨基]苊）与 4,4'-联吡啶（4、4'-联吡）和 1,3-双（4-吡啶基）丙烷（Bpp）在 THF 中的反应分别得到了三维配位聚合物[{(Dpp-bian)GaCr(CO)5}{Na(4,4'-联吡)3}]n（II）和[(Dpp-bian)GaCr(CO)4Na(Et2O)(Bpp)1,5]n（III）。化合物 II 和 III 通过元素分析、核磁共振和红外光谱进行了表征。通过 X 射线衍射（CCDC 编号：2278024）确定了 II 的分子结构。
期刊介绍：
Russian Journal of Coordination Chemistry is a journal that publishes reviews, original papers, and short communications on all aspects of theoretical and experimental coordination chemistry. Modern coordination chemistry is an interdisciplinary science that makes a bridge between inorganic, organic, physical, analytical, and biological chemistry.
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